AI for Science

The best-worst method is a well-known distance based multi-criteria decision-making method used for computing the weights of decision criteria. This article provides a comprehensive analytical examination of the taxicab distance based model of the method, with the objectives of investigating the uniqueness of these solutions, and performing a rigorous consistency analysis. To achieve this, an optimal modification based optimization problem, equivalent to the original one, is first formulated. This reformulated problem is then solved analytically, and the optimal weight sets are derived from its solutions. Contrary to the prevailing understanding derived from numerical experiments with the taxicab model, our analytical framework proves that the model can, in fact, lead to multiple optimal weight sets, and we formally establish the conditions for this occurrence. A mixed-integer linear programming model is then employed to compute the consistency index. A decision-maker-aided selection strategy is also proposed for addressing non-uniqueness of optimal weight sets. In addition, threshold values of the consistency ratio to assess the admissibility of given preferences are also established. This framework provides a solid mathematical foundation that enhances the understanding of the model and eliminates the requirement for optimization software. By significantly improving the model's computational efficiency, it enables implementation in large-scale, dynamic real-world applications such as electricity market bidding strategies and portfolio rebalancing under market volatility. The effectiveness of the proposed framework is demonstrated through numerical examples, and its practical applicability is illustrated via a smartphone selection problem.

The paper establishes results following two interconnected directions. 1. Let $G$ be a Roelcke precompact closed subgroup of the group $\mathrm{Sym}(ω)$ of permutations of the natural numbers. Let $\mathrm{Aut}(G)$ denote the group of continuous automorphisms of $G$. Then $\mathrm{Inn}(G)$ is closed in $\mathrm{Aut}(G)$, where $\mathrm{Aut}(G)$ carries the topology of pointwise convergence for its (faithful) action on the cosets of open subgroups. Under the stronger hypothesis that~$G$ is oligomorphic, $\+ N_G/G$ is profinite, where $\+ N_G$ denotes the normaliser of~$G$ in $\mathrm{Sym}(ω)$, and the topological group $\mathrm{Out}(G)= \mathrm{Aut}(G)/\mathrm{Inn}(G)$ is totally disconnected, locally compact. 2a. We provide a general method to show smoothness of the isomorphism relation for appropriate Borel classes of oligomorphic groups. We apply it to two such classes: the oligomorphic groups with no algebraicity, and the oligomorphic groups with finitely many {essential} subgroups up to conjugacy. 2b. Using this method we also show that if $G$ is in such a Borel class, then $\mathrm{Aut}(G)$ is topologically isomorphic to an oligomorphic group, and $\mathrm{Out}(G)$ is profinite.

Suppose $μ$ and $ν$ are probability measures on $\mathbb{R}$ satisfying $μ\leq_{cx} ν$. Let $a$ and $b$ be convex functions on $\mathbb{R}$ with $a \geq b \geq 0$. We are interested in finding $$\sup_{\mathbf{M}} \sup_τ \mathbb{E}^{\mathbf{M}} \left[ a(X) I_{ \{ τ= 1 \} } + b(Y) I_{ \{ τ= 2 \} } \right] $$ where the first supremum is taken over consistent models $\mathbf{M}$ (i.e., filtered probability spaces $(Ω, \mathbf{F}, \mathbb{F}, \mathbb{P})$ such that $Z=(z,Z_1,Z_2)=(\int_{\mathbb{R}} x μ(dx) = \int_{\mathbb{R}} y ν(dy), X, Y)$ is a $(\mathbb{F},\mathbb{P})$ martingale, where $X$ has law $μ$ and $Y$ has law $ν$ under $\mathbb{P}$) and $τ$ in the second supremum is a $(\mathbb{F},\mathbb{P})$-stopping time taking values in $\{1,2\}$. Our contributions are first to characterise and simplify the dual problem, and second to completely solve the problem under some structural assumptions on the measures $μ$ and $ν$ (namely that $μ$ and $ν$ are absolutely continuous probability measures that satisfy the Dispersion Assumption). A key finding is that the canonical set-up in which the filtration is that generated by $Z$ is not rich enough to define an optimal model and additional randomisation is required. This holds even though the marginal laws $μ$ and $ν$ are atom-free. The problem has an interpretation of finding the robust, or model-free, no-arbitrage bound on the price of a Bermudan option with two possible exercise dates, given the prices of co-maturing European options.

Piecewise-Deterministic Markov Processes (PDMPs) hold significant promise for sampling from complex probability distributions. However, their practical implementation is hindered by the need to compute model-specific bounds. Conversely, while Hamiltonian Monte Carlo (HMC) offers a generally efficient approach to sampling, its inability to adaptively tune step sizes impedes its performance when sampling complex distributions like funnels. To address these limitations, we introduce three innovative concepts: (a) a Metropolis-adjusted approximation for PDMP simulation that eliminates the need for explicit bounds without compromising the invariant measure, (b) an adaptive step size mechanism compatible with the Metropolis correction, and (c) a No U-Turn Sampler (NUTS)-inspired scheme for dynamically selecting path lengths in PDMPs. These three ideas can be seamlessly integrated into a single, `doubly-adaptive' PDMP sampler with favourable robustness and efficiency properties.

In our series of papers, we prove that smooth Fano threefolds in positive characteristic lift to the ring of Witt vectors. Moreover, we show that they satisfy Akizuki-Nakano vanishing, $E_1$-degeneration of the Hodge to de Rham spectral sequence, and torsion-freeness of Crystalline cohomologies. In this paper, we establish these results for the case when $|-K_X|$ is very ample and the Picard group is generated by $ω_X$.

It is well-known that the Sobolev spaces $W^{k,p}(\mathbb R^d)$ are vector lattices with respect to the pointwise almost everywhere order if $k \in \{0,1\}$, but not if $k \ge 2$. In this note, we consider negative $k$ and show that the span of the positive cone in $W^{k,p}(\mathbb R^d)$ is a vector lattice in this case. We also prove a related abstract result: if $(T(t))_{t \in [0,\infty)}$ is a positive $C_0$-semigroup on a Banach lattice $X$ with order continuous norm, then the span of the cone $X_{-1,+}$ in the extrapolation space $X_{-1}$ is a vector lattice. This complements results obtained by Bátkai, Jacob, Wintermayr, and Voigt in the context of perturbation theory and provides additional context for the theory of infinite-dimensional positive systems.

Classical results of Cauchy and Dehn imply that the 1-skeleton of a convex simplicial polyhedron $P$ is rigid i.e. every continuous motion of the vertices of $P$ in $\mathbb R^3$ which preserves its edge lengths results in a polyhedron which is congruent to $P$. This result was extended to convex smplicial polytopes in $\mathbb R^d$ for all $d\geq 3$ by Whiteley, and to generic realisations of 1-skeletons of simplicial $(d-1)$-manifolds in $\mathbb R^{d}$ by Kalai for $d\geq 4$ and Fogelsanger for $d\geq 3$. We will generalise Kalai's result by showing that, for all $d\geq 4$ and any fixed $1\leq k\leq d-3$, every generic realisation of the $k$-skeleton of a simplicial $(d-1)$-manifold in $\mathbb R^{d}$ is volume rigid, i.e. every continuous motion of its vertices in $\mathbb R^d$ which preserves the volumes of its $k$-faces results in a congruent realisation. In addition, we conjecture that our result remains true for $k=d-2$ and verify this conjecture when $d=4,5,6$.

This text is a survey on symmetric matrices. It serves as a script for a module to be taught at university.

The drastic changes in the global economy, geopolitical conditions, and disruptions such as the COVID-19 pandemic have impacted the cost of living and quality of life. It is essential to comprehend the long-term implications of the cost of living and quality of life in major economies. A transparent and comprehensive living index must include multiple dimensions of living conditions. In this study, we present an approach to quantifying the quality of life through the Global Ease of Living Index that combines various socio-economic and infrastructural factors into a single composite score. Our index utilises economic indicators that define living standards, which could help in targeted interventions to improve specific areas. We present a machine learning framework to address missing data for certain economic indicators in specific countries. We then curate and update the data and use a dimensionality reduction approach (Principal Component Analysis and Factor Analysis) to create the Ease of Living Index for major economies since 1970. Our work significantly adds to the literature by offering a practical tool for policymakers to identify areas needing improvement, such as healthcare systems, employment opportunities, and public safety. Our approach with open data and code can be easily reproduced and applied to various contexts, providing transparency and accessibility for ongoing research and policy development in quality-of-life assessment.

Previous work of Chan--Church--Grochow and Baker--Wang shows that the set of spanning trees in a plane graph $G$ is naturally a torsor for the Jacobian group of $G$. Informally, this means that the set of spanning trees of $G$ naturally forms a group, except that there is no distinguished identity element. We generalize this fact to graphs embedded on orientable surfaces of arbitrary genus, which can be identified with ribbon graphs. In this generalization, the set of spanning trees of $G$ is replaced by the set of spanning quasi-trees of the ribbon graph, and the Jacobian group of $G$ is replaced by the Jacobian group of the associated regular orthogonal matroid $M$ (along with an associated regular representation of $M$). Our proof shows, more generally, that the family of "BBY torsors" constructed by Backman--Baker--Yuen and later generalized by Ding admit natural generalizations to (regular representations of) regular orthogonal matroids. In addition to shedding light on the role of planarity in the earlier work mentioned above, our results represent one of the first substantial applications of orthogonal matroids (also called "even delta-matroids" or "Lagrangian orthogonal matroids") to a natural combinatorial problem about graphs.

We prove that the minimal size $M(π_n)$ of a maximal matching in the permutahedron $π_n$ is asymptotically $n!/3$. On the one hand, we obtain a lower bound $M(π_n) \ge n! (n-1) / (3n-2)$ by considering $4$-cycles in the permutahedron. On the other hand, we obtain an asymptotical upper bound $M(π_n) \le n!(1/3+o(1))$ by multiple applications of Hall's theorem (similar to the approach of Forcade (1973) for the hypercube) and an exact upper bound $M(π_n) \le n!/3$ by an explicit construction. We also derive bounds on minimum maximal matchings in products of permutahedra.

Equitable access to essential urban services is a pillar of modern planning, yet most accessibility models rely strictly on static residential locations, ignoring how demand shifts throughout the daily loop. This study introduces a population-based, temporally differentiated framework to examine the resulting "moving target" of urban equity, focusing on medical facilities and green spaces in Hefei, China. Utilising large-scale mobile phone GPS data, we construct dynamic residential and workplace population exposure surfaces to capture shifting hourly demand. We then evaluate accessibility via network-based travel times paired with a novel per-capita provision metric that accounts for real-time demand competition. We define \textit{double disadvantage} as the co-occurrence of poor spatial accessibility and insufficient per-capita service availability. Counterintuitively, the results reveal that double-disadvantaged areas cluster primarily along the inner suburban belt rather than the remote periphery, where per-capita service provision remains relatively sufficient. Furthermore, temporal shifts drastically alter equity landscapes: daytime workplace concentrations intensely exacerbate demand competition in urban job centres. These findings demonstrate that urban inequality depends heavily on spatiotemporal population flows rather than just the fixed location of services. Ultimately, achieving true urban equity requires dynamic planning interventions that address time-varying demand rather than focusing solely on static, home-based metrics.

Increasing optical communication capacity without proportionally increasing receiver complexity remains a key challenge for direct-detection links. Conventional systems typically assign wavelength, polarization and intensity to fixed, separately recovered functions, so that alphabet expansion is accompanied by additional demultiplexing, polarization handling, receiver branches and electronic processing. Here we introduce a unified resource-pool architecture for high-dimensional direct-detection optical communication, in which wavelength, polarization and intensity are jointly organized as a composite optical symbol space and recovered through optical-domain joint projection rather than dimension-by-dimension separation. The receiver is implemented with an integrated disordered photonic processor that transforms each composite optical state into a reproducible multi-output electrical fingerprint for single-shot direct recovery. In a dual-wavelength transmission experiment, the system resolves 4096 composite symbols, corresponding to 12 bits per symbol slot, with a bit error rate of 4.25e-4 after 10 km standard-fiber transmission. Additional experiments demonstrate dense polarization alphabets, wavelength-indexed state-space expansion and high-launch-power operation over hollow-core fiber. These results establish disorder-enabled joint projection in an integrated photonic processor as a route to hardware-efficient high-dimensional direct-detection communication beyond conventional dimension-partitioned receiver architecture.

In the last years, an anomalously high spreading of West Nile virus (WNV) has been observed in Italy, with particularly high peaks of infections in southern Lazio, Campania and Veneto regions. The main disease vector for WNV is represented by Culex pipiens mosquitoes, which spread human infections through their bites. Here, we investigate WNV fever epidemic diffusion during summer season 2025 in Italy through a computational approach based on a quantum version of the Game of Life (GOL) cellular automaton model. Specifically, human dynamics evolves according to the GOL rules, while stochastic dynamics of disease vectors, i.e., mosquitoes, as well as their interaction with humans, simultaneously occur. We show that this model fits the curves of cumulative infected individuals with high accuracy, either at local and average-regional level, with only optimization of mosquito birth and removal rates parameters. Furthermore, leveraging model flexibility, we show that changes in model parameters values elucidate system response to environmental variations. For instance, we quantify, e.g., the impact of mosquito spreading containment measures or sudden mosquito increasing abundance due to climatic and ecological changes. Overall, we provide a general, quantitative description of WNV infection spreading in Italy which could represent a supportive tool to test different environmental scenarios and could be useful to devise strategies for decision makers to monitor disease vector dynamics and to control consequent virus diffusion.

Superconductors are many-body quantum states in which current flows without dissipation. Theory predicts that supercurrents follow a relatively simple spatial pattern in both conventional and unconventional superconductors. Recent studies into the AV3Sb5 (A = Cs, K, Rb) family of Kagome superconductors indicate that CsV3Sb5 has unconventional transport properties that cannot be accounted for with these simple theories, including reports of intrinsic Josephson junctions, higher order Cooper pairing and the zero field diode effect. Attempts to interpret these findings have focused on the interplay of superconductivity with the unconventional charge density wave (CDW) order in these materials, with which superconductivity competes. A current roadblock to understanding how these kagome superconductors give rise to their intriguing properties is the lack of spatially resolved information about transport. Here we show, using a recently developed superconducting quantum interference device (SQUID) microscope, that flakes of CsV3Sb5-xSnx host a network of narrow supercurrent channels. These supercurrent channels emerge at the critical temperature and remain stable for all temperatures and currents. Their non-linear behaviour is consistent with a network of Josephson junctions linked by narrow supercurrent filaments, which naturally leads to the observed transport anomalies. Intriguingly, these observations are much weaker in undoped samples, which suggests links to the physics of charge density waves, disorder, and electronic correlations, all of which are greatly influenced by the doping strength. These results establish new frontiers for the local investigation of charge transport and competing orders in strongly correlated electron systems, and shine a new light on the anomalous transport properties of the AV3Sb5 kagome superconductors.

We investigate terahertz (THz) harmonic generation in the InSb/CdTe heterostructure, demonstrating, for the first time, efficient in-plane magnetic field-induced second-harmonic generation (SHG). We also achieve significant third-harmonic generation (THG), rivalling Dirac materials such as graphene and Cd3As2. Our theoretical analysis identifies the primary SHG mechanism as the orbital-Zeeman correction to Drude conductivity, while the dominant THG contribution also shows Drude-like behavior. The results provide a general route to efficient THz harmonic generation in high mobility materials.

We propose a scheme for realizing thermal logic gates at the nanoscale using a phononic ring system. Two atomic sites, placed in close proximity to the ring, serve as the inputs for two-input logic operations, while a single proximity site is employed for single-input logic functionality. The logic output is encoded in the phonon transmission probability, which is calculated within the framework of non-equilibrium Green's function formalism. By appropriately tuning the ring-electrode junction configuration, all seven standard logic gates, comprising three fundamental and four combinatorial operations, are successfully realized in different phonon frequency regimes. Our results suggest that the proposed logic operations remain valid over a broad range of phonon frequencies, highlighting the generality and reliability of the proposed approach.

A magnetic skyrmion tube is a three-dimensional topological soliton formed by stacking two-dimensional skyrmions along the out-of-plane direction. Recent real-space observations of skyrmion tubes have stimulated growing interest in their dynamics and emergent properties. Here, we go beyond simple skyrmion stacking and investigate how a ``twist" introduced along the tube direction affects the dynamics and emergent responses of skyrmion tubes. We find that such a twist can be created as a localized texture, termed a twist soliton, through thermal quench dynamics. By complementarily combining large-scale numerical simulations with analytical calculations based on collective coordinates, we clarify its current-driven nonlinear motions that depend on its twist chirality. Remarkably, its velocity can be substantially enhanced by a magnetic-field component perpendicular to the tube. Furthermore, the associated emergent electric field enables identification of the twist soliton, including the sign of its chirality, through Hall measurements. Our results reveal the twist degree of freedom as an essential ingredient of skyrmion-tube physics and pave the way for the development of spintronic devices exploiting the three-dimensional nature of spin textures.

For a non-zero parameter $q$, we define Hermite trace polynomials, which are multivariate polynomials indexed by permutations. We prove several combinatorial properties for them, such as expansions and product formulas. The linear functional determined by these trace polynomials is a state for $q = \frac{1}{N}$ for $N$ a non-zero integer. For such $q$, Hermite trace polynomials of different degrees are orthogonal. The product formulas extend to the closure with respect to the state. The state can be identified with the expectation induced by the $N \times N$ Hermitian Brownian motion. Hermite trace polynomials are martingales for this Brownian motion, while the elements in the closure can be interpreted as stochastic integrals with respect to it. Using the grading on the algebra, we prove several chaos decompositions for such integrals, as well as analyze corresponding creation and annihilation operators. In the univariate, pure trace polynomial case, trace Hermite polynomials can be identified with the Hermite polynomials of matrix argument.

The sparse analogue of Szemerédi's regularity method has played a central role in the development of extremal results for random graphs. While the sparse embedding lemma (the KLR conjecture) has been resolved, the corresponding sparse counting lemma remains widely open. The conjecture, formulated by Gerke, Marciniszyn, and Steger, states that for every fixed graph $H$ and any $β>0$, there exists $\varepsilon>0$ such that the following holds. Consider a balanced blow-up of $H$ with vertex classes of size $n$, where each pair corresponding to an edge of $H$ forms an $(\varepsilon)$-regular bipartite graph with exactly $m$ edges. Assume that $m$ is above the natural threshold $m \gg n^{2-1/m_2(H)}$, then all but a $β^m$ proportion of such graphs contain at least $(1-δ)$ times the expected number of copies of $H$. In this paper, we establish the $H=K_4$ case of the conjecture.

The integration of photonic components into surface ion traps provides a scalable approach for trapped-ion quantum computing, sensing, and metrology, enabling compact systems with enhanced stability and precision. However, the introduction of optical apertures in the trap electrodes can distort the trapping electric field. This can lead to excess micromotion (EMM) and ion displacement which degrade the performance of quantum logic operations and optical clocks. In this work, we systematically investigate the electric field distortion in a surface ion trap with integrated waveguides and grating couplers using Finite Element Method (FEM) simulations. We analyze methods to reduce these distortions by exploiting symmetries and transparent conductive oxide materials.

The Schur index of a $4$ dimensional $\mathcal{N}=2$ superconformal field theory counts (with sign) bosonic and fermionic states that preserve $4$ supercharges. We consider the Schur indices of $4$d $\mathcal{N}=4$ super Yang-Mills and $\mathcal{N}=2$ circular quiver gauge theories with gauge groups $U(N)$ or $SU(N)$. We calculate the exponentially dominant part of their asymptotic expansions as the index parameter $q$ approaches any root of unity. We find that some of the indices exhibit ``small" ($\mathcal{O}(N^0)$ as $N \rightarrow \infty$) exponential growth, which is much smaller than an $\mathcal{O}(N^2)$ exponential growth of states that is indicative of a black hole. This implies that the indices do not capture a growth of states that would correspond to a supersymmetric black hole that preserves 4 supercharges in the holographic dual AdS theory. Interestingly, the exponentially dominant part in the Schur asymptotics we consider, depends on the parity of the rank $N$.

In this paper, we derive a generalized second fluctuation-dissipation theorem (FDT) for stochastic dynamical systems in the steady state. The established theory is built upon the Mori-type generalized Langevin equation for stochastic dynamical systems and only uses the properties of the Kolmogorov operator. The new second FDT expresses the memory kernel of the generalized Langevin equation as the correlation function of the fluctuation force plus an additional term. In particular, we show that for nonequilibrium states such as heat transport between two thermostats with different temperatures, the classical second FDT is valid even when the exact form of the steady state distribution is unknown. The obtained theoretical results enable us to construct a data-driven nanoscale fluctuating heat conduction model based on the second FDT. We numerically verify that the new model of heat transfer yields better predictions than the Green-Kubo formula for systems far from the equilibrium.

Laminar-to-turbulent transition delay is a key challenge in hypersonic boundary-layer flows. Unstable disturbances-most prominently the first and second modes-trigger the onset of turbulence and pose a fundamental technological barrier to hypersonic transport. While existing control strategies target the second mode, simultaneous mitigation of the first mode has long appeared physically impossible. A new flow-control concept is introduced in which phase relations between wall pressure and velocity fluctuations are tailored using subsurface phonon engineering to control both modes concurrently. The outcome is substantial drag reduction and alleviation of the extreme thermal loads associated with turbulence.

Urban venues serve as arenas for social mixing. While residential and activity-space segregation have been extensively studied, less is known about how the spatial structure of cities, particularly public transit infrastructure, shapes the geography of social mixing at specific locations. This study examines how transit accessibility associates with visitor diversity -- the compositional heterogeneity of visitors sharing a venue, used here as an indicator of social mixing potential -- at points of interest (POIs) in nine cities in Sweden and three cities in the United States (New York, Washington DC, Atlanta). Using mobile phone GPS data in 2024, we compute visitor diversity indices based on the birth background composition of visitors' home neighborhoods. Transit catchment diversity positively predicts visitor diversity, but this association is robust only in the largest metropolitan areas; in smaller Swedish cities, the coefficient attenuates to insignificance once geographic catchment composition, centrality, and venue density are controlled. Transit-diversity hotspots concentrate not in already diverse venues, but in lower-diversity POIs with lower commercial density, greater distance from transit in US cities, and greater centrality in Sweden. These patterns are consistent with transit infrastructure playing a bridging role, linking diverse populations to venues where alternative pathways are limited.

We revisit size controllability results in Pötscher and Preinerstorfer (2025) concerning heteroskedasticity robust test statistics in regression models. For the special, but important, case of testing a single restriction (e.g., a zero restriction on a single coefficient), we povide a necessary and sufficient condition for size controllability, whereas the condition in Pötscher and Preinerstorfer (2025) is, in general, only sufficient (even in the case of testing a single restriction).

Time dependence is a universal phenomenon in nature, and a variety of mathematical models in terms of dynamical systems have been developed to understand the time-dependent behavior of real-world problems. Originally constructed to analyze the topological persistence over spatial scales, persistent homology has rarely been devised for time evolution. We propose the use of a new filtration function for persistent homology which takes as input the adjacent oscillator trajectories of a dynamical system. We also regulate the dynamical system by a weighted graph Laplacian matrix derived from the network of interest, which embeds the topological connectivity of the network into the dynamical system. The resulting topological signatures, which we call evolutionary homology (EH) barcodes, reveal the topology-function relationship of the network and thus give rise to the quantitative analysis of nodal properties. The proposed EH is applied to protein residue networks for protein thermal fluctuation analysis, rendering the most accurate B-factor prediction of a set of 364 proteins. This work extends the utility of dynamical systems to the quantitative modeling and analysis of realistic physical systems.

A comprehensive methodology is developed to extract electron and hole effective masses in degenerate semiconductors through a simultaneous global fit of carrier concentration dependence of bandgap and plasma energy, explicitly incorporating band nonparabolicity. Broadband spectroscopic ellipsometry combined with Hall effect analyses enables accurate determination of the bandgap, plasma energy and carrier concentrations. The dielectric function of sputtered Al-doped ZnO thin films are modeled in the fundamental absorption region using an Elliott based model with overlapping excitonic transitions and Urbach tails, while free carrier absorption is described by a modified sernelius formula. Wide carrier concentrations are achieved via controlled deposition and post-annealing, revealing changes in electron effective masses and deviations from parabolic dispersion. Two nonparabolic models are compared, Pisarkiewicz, assuming spherically symmetric band with a step-function approximation of the Fermi-Dirac distribution and Nilsson, incorporating thermal and impurity effects. The latter is shown to capture accurately band nonparabolicity, yielding effective masses and nonparabolicity parameter consistent with bandgap evolution. This approach quantitatively separates Burstein-Moss shift and bandgap renormalization, reproducing carrier dependent bandgap shifts across a wide concentration range. Neglecting valence band contributions introduces systematic bias. Bandgap renormalization is further evaluated using plasmon pole and random phase approximations, underscoring the importance of many-body screening. This framework also enables determination of the Mott critical concentration and the fundamental absorption edge onset. Collectively, these results establish a reliable methodology for extracting band-structure parameters and bandgap shifts, extendable to other transparent conducting oxides.

Superatomic graphene platforms host a rich portfolio of flat-band-driven exotic quantum properties, yet their experimental realization remains challenging. Here, we report the bottom-up on-surface synthesis of superatomic graphene using phosphorus-doped triangulene as building blocks. Scanning tunneling microscopy and spectroscopy measurements resolve the well-defined honeycomb lattice of as-fabricated superatomic graphene and demonstrate the characteristic Dirac band and flat band electronic structures. Density functional theory calculations reveal that the flat bands originate from the in-plane p$_x,_y$-like frontier orbitals of the phosphorus-doped triangulene units, leading to intrinsic half-metallic behavior. Furthermore, oxygen functionalization of the molecular precursor enables deterministic modulation of the electronic structure and magnetic ordering. This work establishes a general platform for designing correlated quantum materials with tunable flat band properties.

Solution-processed thin films of colloidal lead halide perovskite (LHP) nanocrystals (NCs) show great potential for the implementation into optoelectronic devices such as light-emitting diodes (LEDs), lasers, and solar cells. However, these hybrid LHP NC solids exhibit non-negligible size and shape polydispersity, which introduces both structural and energetic disorder. Here, we resolve the exciton dynamics in space, time, and energy to elucidate the impact of different forms of disorder (structural and energetic) on exciton transport. We show that the disorder depends sensitively on the length of the alkylamine ligand used in the synthesis. While shorter alkyl chain lengths lead to high polydispersity, longer alkyl chains lead to more monodispersed and smaller particles where quantum confinement becomes more pronounced and, consequently, lead to increased energetic disorder. Strikingly, we find that exciton transport is less efficient in NC solids with long alkyl chain ligands, despite having a significantly more monodisperse ensemble. This demonstrates that energetic disorder, rather than structural disorder, is the dominant factor for predicting exciton transport within these materials. These findings reveal the critical role of ligand engineering in designing high-performance optoelectronic devices based on hybrid LHP NCs, providing new insights into energy transport dynamics in disordered systems and highlighting the versatility of these materials for advanced photonic and optoelectronic applications.