- Journal ref
- Advanced Quantum Technology (Wiley), 2026
AI中文摘要
我们实验研究了自旋反铁磁一维自旋链系统R2BaNiO5(R = Nd, Gd, Er, Dy)的磁卡效应(MCE)。显著的MCE在长程有序之上甚至在顺磁区域被观测到,归因于低维磁摩擦引起磁熵的变化。这种自旋链初生MCE在长程有序之上很少被报道。有趣的是,在长程磁有序之下,对于R = Nd, Dy和Er成员,观察到多种磁卡效应切换从传统到反向(反之亦然),这取决于温度和磁场。然而,Gd成员没有这种MCE切换,因为它是一个S态原子(轨道角动量L = 0)。我们的系统研究显示,晶体电场(CEF)、强自旋轨道耦合(SOC)和稀土离子各向异性之间的相互作用在自旋重取向中起重要作用,导致由于磁性和晶格熵的奇特变化而产生多种MCE切换。Er、Gd、Dy和Nd的最大熵变化分别为7.8、6.8、4.0和1.0 J kg⁻¹ K⁻¹。我们的研究为在d-f耦合自旋反铁磁和自旋链氧化物系统中调节MCE切换和大温度范围内的MCE效应提供了途径。
英文摘要
We have experimentally investigated the magnetocaloric effect (MCE) of a prototype spin-frustrated one-dimensional spin-chain system, the famous Haldane-chain system, R2BaNiO5 (R = Nd, Gd, Er, Dy). The significant MCE is observed far above long-range ordering, even in the paramagnetic region, which is attributed to the change in magnetic entropy due to short-range spin correlation arising from (low-dimensional) magnetic frustration. Such a spin-chain incipient MCE above long-range ordering is rarely reported. Interestingly, multiple magnetocaloric switching from conventional to inverse MCE (and vice versa) are observed below long-range magnetic ordering, as a function of temperature and magnetic field, for the R = Nd, Dy, and Er members. However, such MCE switching is absent in the Gd member, which is an S-state atom (orbital moment L = 0). Our systematic investigation of this series demonstrates that the interplay between crystal-electric field (CEF), strong spin-orbit coupling (SOC) and rare earth anisotropy of R-ions play an important role in spin reorientation, leading to multiple MCE switching due to intriguing changes in magnetic and lattice entropy. The maximum change of entropy for Er, Gd, Dy and Nd is 7.8, 6.8, 4.0 and 1.0 J Kg-1 K-1 respectively. Our study presents a pathway for tuning MCE switching and the MCE effect over large temperature regions in d-f coupled spin-frustrated and spin-chain oxide systems.