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2606.02579 2026-06-02 hep-ph hep-ex

New Windows on Heavy Dark Matter: Mineral Melt Modelling and X-Ray Readout for Muscovite Mica

重暗物质的新窗口:白云母的矿物熔融建模与X射线读出

Yilda Boukhtouchen, Joseph Bramante, Andrew Buchanan, Alexander Hayes, Matthew Leybourne, Jennika McIntosh, Anupam Ray, Aaron Shugar

AI总结 本文提出利用白云母作为古探测器,通过Sedov-Taylor热尖峰模型模拟重复合暗物质穿越云母形成的熔融径迹,并开发基于铜背衬对比的快速X射线荧光映射读出方法,实现对微米级损伤特征的大面积扫描,从而为不透明和扩散复合暗物质提供新的探测灵敏度。

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AI中文摘要

白云母是一种半透明的层状硅酸盐矿物,其基面解理、低辐射本底、十亿年曝光时间以及在地质时间尺度上已证实的径迹保留能力,使其成为稀有粒子搜索的有力目标。在这项工作中,我们开发了一个利用白云母作为古探测器探测重复合暗物质的新框架。我们使用Sedov-Taylor热尖峰形式主义对重复合暗物质穿过云母形成的熔融径迹进行建模,并通过核反冲级联的SRIM/TRIM模拟验证亚微米区域,同时校准控制局部能量沉积的声子效率。我们展示了一种新颖的读出方法,即使用铜背衬对比技术的快速X射线荧光映射,能够在宏观扫描区域内识别解理云母片中的微米级损伤特征,并通过激光烧蚀缺陷区域校准最小可探测径迹尺寸。我们给出了不透明和扩散复合暗物质的预计灵敏度,包括对因覆盖层而显著衰减的大复合物的亚熔融孔道探测模式。我们还重新审视了先前基于蚀刻云母搜索的暗物质排除,指出了损害这些约束稳健性的缺陷。

英文摘要

Muscovite mica is a translucent, layered silicate mineral whose basal cleavage, low radiogenic background, gigayear exposures, and demonstrated track retention over geological timescales make it a compelling target for rare particle searches. In this work, we develop a new framework for detecting heavy composite dark matter using muscovite mica as a paleodetector. We model melt track formation by heavy composite dark matter transiting through mica using a Sedov-Taylor thermal spike formalism, and validate the sub-micron regime with SRIM/TRIM simulations of nuclear recoil cascades, which also calibrate the phonon efficiency governing local energy deposition. We demonstrate a novel readout method using rapid X-ray fluorescence mapping with a copper backing contrast technique, capable of identifying micron-scale damage features in cleaved mica sheets over macroscopic scan areas, and calibrate the minimum detectable track size using laser-ablated defect regions. We present projected sensitivities for opaque and diffuse composite dark matter, including a sub-melt hole-channel detection mode for large composites substantially attenuated by overburden. We also revisit prior dark matter exclusions from etched mica searches, identifying shortcomings that compromise the robustness of these constraints.

2606.02571 2026-06-02 physics.optics

Multilayer Babinet metamaterial to initiate nonreciprocal topological phenomena and generalized Faraday rotation

多层巴比涅超材料引发非互易拓扑现象与广义法拉第旋转

Balázs Bánhelyi, Miklós Waldhauser, Virág Szünstein, Ákos Sebők-Pap, Olivér Ardelán, Anna Kőházi-Kis, Dávid Vass, András Szenes, David Keene, Maxim Durach, Mária Csete

AI总结 通过优化巴比涅互补周期性结构的多层球状等离子体纳米谐振器阵列,实现了广义法拉第旋转,并利用对称性破缺、布里渊区折叠和层间耦合等机制,在光谱重叠区域获得非互易旋转和非对称传输。

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Comments
48 pages, 11 + 15 figures
AI中文摘要

由球状等离子体纳米谐振器微阵列构成的巴比涅互补周期结构的多层被优化以确保广义法拉第旋转。由于涉及(i)通过耦合局域模式实现对称性破缺,(ii)由构成面内扭曲耦合环的子晶格引起的布里渊区折叠,(iii)巴比涅互补图案之间的层间耦合等丰富物理机制,在光谱重叠区域实现了非互易旋转和非对称传输。纳米光子学现象包括(i)准BIC共振,(ii)导致时间周期Floquet调制的层级耦合局域和传播模式,(iii)可通过层内和层间参数独立调节的合成势的初始化。独特的双各向异性复合材料产生合成矢量规范和模拟磁场,表现为倾斜进动的磁偶极子及其伴随的时间周期调制,固有地确保了合成维度。在经典意义上,沿量子化平带的非对称传输得到增强,并在与不可逆偏振旋转重叠的有限波长和倾斜区间内的混合基和前向基中得到增强。传输脉冲重塑证明了邻近共振模式的拍频,损耗可通过有源附加层补偿,从而实现法拉第隔离器能力。多层结构在高维合成参数空间中合成了拓扑现象。

英文摘要

Multilayers of Babinet complementary periodic structures constructed with miniarrays of spherical plasmonic nanoresonators were optimized to ensure Generalized Faraday Rotation. Nonreciprocal rotation and asymmetric transmission were achieved in spectrally overlapping regions due to the reach physics involving (i) symmetry breaking via coupled localized modes, (ii) Brillouin zone-folding stemmed from constituent sub-lattices forming in-plane twisted coupled loops, (iii) interlayer coupling between Babinet complementary patterns. The nanophotonical phenomena include (i) quasi-BIC resonances, (ii) hierarchically coupled localized and propagating modes that results in time-periodic Floquet modulation, (iii) initialization of synthetic potentials tuneable independently via intra and inter-layer parameters. The unique bianisotropic composites result in a synthetic vector gauge and emulated magnetic field manifesting itself in tilted-precessing magnetic dipoles and the accompanying modulation being time-periodic, inherently ensures a synthetic dimension. The asymmetric transmission is enhanced in the classical sense along quantized flat bands, and in mixed and forward bases inside finite wavelength-and-tilting intervals overlapping with nonreciprocal polarization rotation. The transmitted pulse re-shaping proves beating of nearby resonant modes, the loss can be compensated with active ad-layers thereby resulting in Faraday isolator capability. The multilayers synthetize topological phenomena in high-dimensional synthetic parameter spaces.

2606.02566 2026-06-02 astro-ph.GA astro-ph.CO hep-ph

Mergers Matter: Gravothermal Collapse in Dwarf Halos with Self-Interacting Dark Matter

合并至关重要:具有自相互作用暗物质的矮星晕中的引力热坍缩

Maya Silverman, Abdelaziz Hussein, Arpit Arora, Mariangela Lisanti, Manoj Kaplinghat, Lina Necib, Andreas Thoyas, Stephanie O'Neil, Robyn E. Sanderson, Xuejian Shen, Jorge Moreno

AI总结 通过模拟六个矮星晕,发现合并事件注入轨道动能改变热输运,导致具有宁静合并历史的星晕发生核心坍缩,而持续合并的星晕则不会坍缩,并可能产生暗物质缺失星系。

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Comments
14 pages, 3 Figures, 3 Tables
AI中文摘要

在相对速度低于$\sim100\,{ m km \, s}^{-1}$时具有大截面的自相互作用暗物质(SIDM)模型可以通过矮星系观测进行检验。我们分析了六个具有不同组装历史的暗物质-only zoom-in $\sim10^{10}\,{ m M}_\odot$星晕,采用截面与质量之比$σ/m = 70\,cm^2 \, g^{-1}$。我们发现合并事件向星晕注入轨道动能,改变了核心的热输运和引力热演化。六个星晕中的三个——那些具有最宁静合并历史的——在这些模拟中显示出清晰的核心坍缩迹象。持续合并的星晕不会坍缩。此外,合并诱导的热输运驱动两个非坍缩星晕的中心密度远低于引力热流体模型的预测。这些发现提出了一种产生暗物质缺失星系的新机制,并扩展了旋转曲线的多样性,超出了仅由星晕浓度预测的范围。因此,合并历史对于理解SIDM中矮星晕的中心密度分布至关重要。

英文摘要

Self-Interacting Dark Matter (SIDM) models with large cross sections at relative velocities below $\sim100\,{\rm km \, s}^{-1}$ can be tested with dwarf galaxy observations. We analyze six dark-matter-only zoom-in $\sim10^{10}\,{\rm M}_\odot$ halos with diverse assembly histories, adopting a cross section over mass of $σ/m = 70\,cm^2 \, g^{-1}$. We find that mergers inject orbital kinetic energy into the halo, altering the heat transport and the gravothermal evolution of the core. Three of the six halos -- those with the most quiescent merger histories -- show clear signs of core collapse in these simulations. Halos with sustained mergers do not collapse. Furthermore, merger-induced heat transport drives two non-collapsing halos to central densities well below the predictions of the gravothermal fluid model. These findings suggest a novel mechanism for producing dark-matter-deficient galaxies and expanding the diversity of rotation curves beyond what halo concentration alone predicts. Merger histories are thus essential for understanding central density distributions of dwarf galaxy halos in SIDM.

2606.02560 2026-06-02 physics.atom-ph cond-mat.quant-gas physics.app-ph physics.optics quant-ph

A Mid-Infrared Platform Based on Strontium Tweezer Arrays

基于锶镊子阵列的中红外平台

Aaron Holman, Ximo Sun, Bojeong Seo, Joshua Corn, Zezheng Zhu, Yuan Xu, Jiahao Wu, Nanfang Yu, Dmytro Filin, Marianna Safronova, Sebastian Will

AI总结 利用光镊阵列中的88Sr原子实现中红外跃迁(2923 nm),通过识别魔幻波长和单原子操控,为研究集体发射现象和偶极多体物理提供平台。

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Comments
10 pages, 7 main figures, 3 appendix figures
AI中文摘要

亚波长原子镊子阵列,其中原子可以放置在比其发射波长更小的距离上,已被提议作为研究集体发射现象(如超辐射和亚辐射)的多功能平台。实验上,这种阵列的实现一直是一个挑战,因为典型的发射波长在可见光或近红外波段,相对于微米量级的典型镊子间距较短。在这里,我们使用光镊阵列中的$^{88}$Sr原子来访问2923 nm($5s5p\:^{3}P_{2} \rightarrow 5s4d\:^{3}D_{3}$)的中红外跃迁。我们识别出597.14(3) nm的魔幻捕获波长,并展示了高保真度的单原子制备和成像。此外,利用2923 nm光,我们演示了镊子捕获锶的分辨边带冷却。除了能够在灵活排列的原子中研究集体发射现象外,我们的平台还为偶极多体物理、对里德伯动力学和锶精细结构量子比特的增强控制提供了新的机会。

英文摘要

Subwavelength atomic tweezer arrays, in which atoms can be positioned at distances smaller than their emission wavelength, have been proposed as a versatile platform to study collective emission phenomena, such as superradiance and subradiance. Experimentally, the realization of such arrays has been a challenge as typical emission wavelengths in the visible or near-infrared are short compared to typical tweezer spacings in the micrometer range. Here, we use $^{88}$Sr atoms in optical tweezer arrays to access a mid-infrared transition at 2,923 nm ($5s5p\:^{3}P_{2} \rightarrow\, 5s4d\:^{3}D_{3}$). We identify a magic trapping wavelength at 597.14(3) nm and demonstrate single-atom preparation and imaging with high fidelity. In addition, using 2,923 nm light, we demonstrate resolved-sideband cooling of tweezer-trapped strontium. Beyond enabling studies of collective emission phenomena in flexible arrangements of atoms, our platform opens novel opportunities for dipolar many-body physics and enhanced control over Rydberg dynamics and the strontium fine-structure qubit.

2606.02557 2026-06-02 physics.ins-det hep-ex

Full Characterization of a Mock Nuclear Waste Barrel with Muon Tomography using Micromegas Detectors

使用Micromegas探测器的缪子层析成像对模拟核废料桶的全面表征

Raphaël Bajou, David Attié, Héctor Gómez, Irakli Mandjavidze, Philippe Mas

AI总结 基于多重库仑散射的缪子层析成像,结合Micromegas探测器,实现了对205升模拟核废料桶内部结构的高精度三维成像和材料鉴别。

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12 pages, 15 figures
AI中文摘要

基于多重库仑散射的缪子层析成像提供了一种利用天然宇宙射线缪子对致密和屏蔽物体进行无损成像的方法。在核废料表征的背景下,我们使用专用的1m$^2$缪子散射层析成像测试台,对205升模拟废料桶进行了实验成像。该系统采用多路复用电阻型Micromegas探测器,实现了稳定且高精度的缪子追踪。首先使用蒙特卡洛模拟来表征材料依赖的散射特征,并通过统计重建定量评估识别性能。然后基于这些模拟结果定义客观判别阈值,并将其应用于实验数据以定位和识别内部异常。使用角度统计重建算法,我们实现了10毫米的空间分辨率,并展示了包含低和高辐射长度材料的内部结构的三维成像。使用接收者操作特征分析评估材料鉴别性能,在数天的采集时间内,对铅和钢等致密金属夹杂物实现了高识别效率(AUC $\geq$ 0.96),同时空腔也表现出强对比度。实验结果与详细的蒙特卡洛模拟吻合良好。通过建立从基于模拟的性能表征到实测数据应用的连续工作流程,这项工作为应用于复杂屏蔽物体的缪子散射层析成像提供了一个定量验证的框架。

英文摘要

Muon tomography based on multiple Coulomb scattering provides a non-destructive method to image dense and shielded objects using naturally occurring cosmic-ray muons. In the context of nuclear waste characterization, we present the experimental imaging of a 205-L mock waste barrel using a dedicated 1m$^2$ muon scattering tomography test bench. The system employs multiplexed resistive Micromegas detectors, enabling stable and high-precision muon tracking. Monte Carlo simulations are first used to characterize material-dependent scattering signatures and to quantitatively assess identification performance using statistical reconstruction. These simulation-based results are then used to define objective discrimination thresholds, which are subsequently applied to experimental data for the localization and identification of internal anomalies. Using an Angle Statistics Reconstruction algorithm, we achieve a spatial resolution of 10 mm and demonstrate the three-dimensional imaging of an internal structure containing both low- and high-radiation length materials. Material discrimination performance is evaluated using receiver operating characteristic analysis, yielding high identification efficiency for dense metallic inclusions such as lead and steel (AUC $\geq$ 0.96) within acquisition times of a few days, while cavities also exhibit strong contrast. Experimental results show good agreement with detailed Monte Carlo simulations. By establishing a continuous workflow from simulation-based performance characterization to practical application on measured data, this work provides a quantitatively validated framework for muon scattering tomography applied to complex, shielded objects.

2606.02554 2026-06-02 physics.plasm-ph

Modeling Torque Induced Alignment in a Dusty Plasma System

尘埃等离子体系统中扭矩诱导对准的建模

Benny Rodriguez Saenz, Diana Jimenez Marti, Lorin Swint Matthews, Truell W. Hyde

AI总结 通过自洽数值模拟研究非规则带电尘埃聚集体在等离子体鞘层中的旋转动力学,发现鞘层电场是旋转的主要驱动力并使其电偶极矩与场方向对齐,离子尾迹则通过轴向和横向分量分别产生对抗扭矩和失稳贡献。

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AI中文摘要

浸入等离子体鞘层中的非规则尘埃聚集体经历若干依赖方向的扭矩,这些扭矩可改变其旋转动力学和稳定性。本文利用自洽数值模拟,在代表GEC射频等离子体电池的条件下,研究了带电非规则聚集体的旋转动力学。聚集体在驱动离子流的单向鞘层电场中自由旋转,使得运动过程中作用于聚集体的扭矩贡献得以评估。结果表明,鞘层电场是旋转的主要驱动力,并使聚集体的电偶极矩与鞘层电场方向对齐。离子尾迹改变了这种对准:其轴向场分量产生对抗扭矩,而横向分量引入失稳贡献,导致在平衡取向附近出现小幅度振荡。旋转平衡由相互作用能阱描述,其弹簧常数和深度随鞘层电场强度增加而增大,表明在较高场强下对准更强且对角度扰动的抵抗力更大。聚集体-离子相互作用的二阶多极展开表明,偶极项主导了离子对对准扭矩的贡献,支持在所考察条件下采用偶极离子近似。这些结果将鞘层电场确定为非规则聚集体旋转的主要稳定机制,并阐明了离子尾迹场如何扰动平衡取向。

英文摘要

Irregular dust aggregates immersed in plasma sheaths experience several orientation-dependent torques that can modify their rotational dynamics and stability. Here, we investigate the rotational dynamics of charged irregular aggregates under conditions representative of a GEC rf plasma cell using self-consistent numerical simulations. The aggregates rotate freely in a unidirectional sheath electric field that drives an ion flow, allowing the torque contributions acting on the aggregate to be evaluated throughout the motion. The results show that the sheath electric field is the main driver of rotation and aligns the aggregate electric dipole moment with the sheath field direction. The ion wake modifies this alignment: its axial field component produces an opposing torque, while its transverse components introduce a destabilizing contribution that leads to small oscillations about the equilibrium orientation. The rotational equilibrium is described by an interaction energy well whose spring constant and depth increase with the sheath electric field magnitude, indicating stronger alignment and greater resilience to angular perturbations at higher fields. A second order multipole expansion of the aggregate ion interaction shows that the dipolar term governs the ion contribution to the aligning torque, supporting a dipole ion approximation across the examined conditions. These results identify the sheath electric field as the principal stabilizing mechanism for irregular aggregate rotation and clarify how ion wake fields perturb the equilibrium orientation.

2606.02550 2026-06-02 stat.AP physics.ao-ph

Probabilistic storyline attribution using machine learning

使用机器学习的概率性故事线归因

Frieder Loer, Maybritt Schillinger, Sebastian Sippel

AI总结 提出分布自编码器(DAE)方法,基于大气环流状态和全球变暖水平生成气候反事实,用于概率性故事线归因,并以2003年欧洲热浪为例展示了条件强度和概率比的变化。

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main text: 19 pages and 4 figures
AI中文摘要

气候归因的一个基本目标是估计强迫气候变化如何影响观测到的极端天气事件。故事线归因方法将观测到的天气事件(以其大气动态状态即大气环流为条件)与当前“事实”气候中的事件进行比较,并与假设的“反事实”气候中具有非常相似环流条件的事件进行比较。然而,物理气候模型无法直接在不同气候强迫状态下转移这些故事线反事实。统计和机器学习技术可能克服这一限制;然而,在不同气候状态下模拟环流条件极端事件具有挑战性。在这里,我们展示了分布自编码器(DAE)作为一种生成气候反事实的通用方法。它们以大气环流状态和平均全球变暖水平为条件,对欧洲空间分辨温度场的完整分布进行建模。这些分布允许推导有意义的条件概率比,这是基于DAE的故事线方法的一个特殊优势。我们在完全耦合的气候模型模拟上训练DAE,并评估在不同事实和基于故事线的反事实气候模型模拟中的建模分布。在一个说明性案例研究中,我们重新审视了2003年欧洲热浪,并使用ERA5环流为假设的“类似2003年的欧洲热浪”生成反事实,我们假设该热浪发生在2003年后的四分之一世纪(2028年)和半个世纪(2053年)。条件强度将从2003年的29.3°C增加到2028年的30.3°C和2053年的32.1°C,与2003年相比,条件概率比分别为2.1和3.2。

英文摘要

A fundamental goal in climate attribution is to estimate how forced climate change contributes to observed extreme weather events. The storyline attribution method compares an observed weather event, conditional on its atmospheric dynamic state (i.e., atmospheric circulation), in the current, 'factual' climate to an event with very similar circulation conditions in a hypothetical, 'counterfactual' climate. However, physical climate models cannot directly transfer these storyline counterfactuals across different climate forcing states. Statistical and machine learning techniques may overcome this limitation; yet, emulating circulation-conditional extreme events under different climate states is challenging. Here, we demonstrate distributional autoencoders (DAEs) as a versatile method for generating climate counterfactuals. They model the full distribution of spatially resolved European temperature fields conditional on the atmospheric circulation state and the mean global warming level. These distributions allow for deriving meaningful conditional probability ratios, which is a particular advantage of the DAE-based storyline approach. We train DAEs on fully coupled climate model simulations and we evaluate the modelled distributions across different factual and storyline-based counterfactual climate model simulations. In an illustrative case study, we revisit the 2003 European heatwave and we generate counterfactuals for a hypothetical `2003-like European heatwave' using ERA5 circulation, which we hypothesize to occur a quarter century (2028) and a half century (2053) after 2003. The conditional intensity would increase from 29.3 °C in 2003, to 30.3 °C and 32.1 °C in 2028 and 2053, respectively and conditional probability ratios would be 2.1 and 3.2 when compared to 2003.

2606.02549 2026-06-02 physics.chem-ph physics.atom-ph physics.comp-ph

Diagrammatic Monte Carlo for positron-molecule many-body theory

正电子-分子多体理论的图解蒙特卡洛方法

T. A. Scott, S. K. Gregg, D. G. Green

AI总结 提出图解蒙特卡洛方法随机采样梯级级数贡献,通过Cesáro-Riesz重求和外推至无穷阶,实现正电子-分子关联势的高效计算,并在氢化锂基准测试中与精确对角化定量一致。

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AI中文摘要

本文提出了一种图解蒙特卡洛方法,用于评估分子场中正电子关联势(自能)的梯级级数贡献。在Tamm-Dancoff近似下,对$GW$@TDHF、虚正电子素($T$矩阵)和正电子-空穴Goldstone梯级级数贡献逐阶随机采样,其中后两类在该近似下是精确的,并使用Cesáro-Riesz重求和外推至无穷阶。采用高斯基组,通过密度拟合表示库仑矩阵元,三中心积分是需存储在内存中的最大数组。与精确求解Bethe-Salpeter方程[J. Hofierka, B. Cunningham, C. M. Rawlins, C. H. Patterson and D. G. Green, Nature {f 606}, {688} (2022)]相比,该随机方法将所需最大数组的内存减少了约基组中分子轨道数$N\sim10^2$--$10^3$量级。氢化锂的基准测试结果与精确对角化定量一致,尤其成功实现了虚正电子素无穷电子-正电子梯级级数的随机求和。

英文摘要

A diagrammatic Monte Carlo evaluation of the ladder series contributions to the correlation potential (self energy) of a positron in the field of a molecule is presented. The $GW$@TDHF, virtual-positronium ($T$-matrix), and positron-hole Goldstone ladder series contributions are stochastically sampled order-by-order within the Tamm-Dancoff approximation, which is exact for the latter two classes, with Ces{á}ro-Riesz resummation used to extrapolate to infinite order. Gaussian bases are employed and Coulomb matrix elements are represented via density fitting, with the three centre integrals the largest arrays required to be stored in memory. The stochastic approach thus realizes a reduction in memory of the largest arrays required on the order of the number of molecular orbitals in the basis $N\sim$10$^2$--10$^3$ compared to the exact deterministic solution of Bethe-Salpeter equations [J. Hofierka, B. Cunningham, C. M. Rawlins, C. H. Patterson and D. G. Green, Nature {\bf 606}, {688} (2022)]. Benchmark results for lithium hydride show quantitative agreement with exact diagonalisation, notably demonstrating the successful stochastic summation of the virtual-positronium infinite electron-positron ladder series.

2606.02543 2026-06-02 physics.atom-ph

Suppression of differential light shifts in ground and metastable trapped-ion qubits

基态和亚稳态囚禁离子量子比特中差分光移的抑制

Drew Parks, Thomas Dellaert, Patrick McMillin, Conrad Roman, Andrei Derevianko, Wesley C. Campbell

AI总结 本文通过极化调控实现“魔幻”偏振条件,抑制了高功率离共振激光在基态和亚稳态时钟量子比特中的差分光移,并展示了亚稳态量子比特的高保真度操控。

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Comments
9 pages, 5 figures
AI中文摘要

在磁场存在下,超精细时钟量子比特可能获得矢量差分光移,该光移可通过极化调谐以抑制高功率离共振激光的总差分光移。我们实验测量了这种“魔幻”偏振条件,抑制了$^{171}\mathrm{Yb}^+$的${}^2\mathrm{S}_{1/2}$基态和${}^2\mathrm{F}_{7/2}^o$亚稳态时钟量子比特中的差分光移。我们计算了抑制常见囚禁离子种类基态时钟量子比特中差分光移所需的最小偏置磁场,发现其低于实验中通常已存在的场强。我们还提出了$^{171}\mathrm{Yb}^+$中亚稳态时钟量子比特的控制方法,展示了状态制备和测量保真度$2.9^{+3.0}_{-1.5} imes10^{-4}$($-35 \pm 4 \, \mathrm{dB}$)。

英文摘要

In the presence of a magnetic field, hyperfine clock qubits can acquire a vector differential light shift that can be tuned via polarization to suppress the total differential light shift of high-power, off-resonant laser light. We experimentally measure this "magic" polarization condition, suppressing differential light shifts in both the ${}^2\mathrm{S}_{1/2}$ ground and ${}^2\mathrm{F}_{7/2}^o$ metastable clock qubits of $^{171}\mathrm{Yb}^+$. We present calculations of the minimum bias magnetic fields required to suppress differential light shifts in the ground state clock qubits of commonly trapped ion species, finding that they are below the strengths of fields already typically present in experiments. We further present methods for metastable clock-qubit control in $^{171}\mathrm{Yb}^+$, demonstrating a state preparation and measurement infidelity of $2.9^{+3.0}_{-1.5}\times10^{-4}$ ($-35 \pm 4 \, \mathrm{dB}$).

2606.02542 2026-06-02 quant-ph

Chutes and Ladders: Dynamical Automorphisms via the ZX-Calculus

梯子与滑道:通过ZX-演算的动态自同构

Alexander Frei, Sascha Zakaib-Bernier, Zachary Mann, Michael Vasmer, Victor V. Albert

AI总结 本文扩展ZX-演算以处理Floquet和其他动态稳定子码,通过测量基代码切换与规范固定的联系,实现稳定子码空间中的闭环,从而构造逻辑Clifford门,并作为示例实现了七量子比特裸码的距离保持逻辑相位门。

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Comments
32 pages, 10 figures
AI中文摘要

ZX-演算是一种用于操纵量子电路的强大图形语言,最近在量子纠错中发现了许多应用。我们通过测量基代码切换与规范固定之间的联系(arXiv:1810.10037),扩展了这种语言以处理Floquet和其他动态稳定子码。我们组合规范固定步骤,在稳定子码空间中实现闭环,返回到原始代码空间,相差一个逻辑Clifford门。这些在稳定子码空间中的基于测量的路径可以被视为相对于单量子比特Clifford操作和量子比特置换的捷径,或“梯子与滑道”。这提供了一种机器可解释的方法来构造动态自同构,并有助于搜索所需逻辑门的实现。作为示例,我们通过七量子比特裸码(arXiv:1702.01155)的距离保持代码切换实现了一个逻辑相位门,该码没有基于单量子比特Clifford操作和量子比特置换的非平凡逻辑Clifford门(arXiv:2409.18175)。

英文摘要

The ZX-calculus is a powerful graphical language for manipulating quantum circuits, which has recently found many applications in quantum error correction. We extend this language to handle Floquet and other dynamical stabilizer codes via the connection between measurement-based code switching and gauge fixing (arXiv:1810.10037). We combine gauge-fixing steps to implement a closed loop in the space of stabilizer codes, returning to the original codespace up to a logical Clifford gate. These measurement-based paths in the space of stabilizer codes can be viewed as shortcuts, or "chutes and ladders", relative to single-qubit Clifford operations and qubit permutations. This yields a machine-interpretable method for constructing dynamical automorphisms and facilitates the search for implementations of desired logical gates. As an example, we implement a logical phase gate via distance-preserving code switching for the seven-qubit code bare code (arXiv:1702.01155), which has no non-trivial logical Clifford gates based on single-qubit Clifford operations and qubit permutations (arXiv:2409.18175).

2606.02539 2026-06-02 astro-ph.CO gr-qc hep-ph

JWST's Little Red Dots as collapsed Supermassive Dark Stars

JWST的小红点作为坍缩的超大质量暗星

Cosmin Ilie

AI总结 提出超大质量暗星(SMDSs)作为准星(quasi-star)的前身,通过暗物质湮灭而非核燃烧提供能量,自然满足准星形成所需的结构和能量条件,从而解释JWST观测到的“小红点”(LRDs)现象。

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AI中文摘要

“小红点”(LRDs)的本质是JWST数据提出的最深奥谜团之一。能够再现观测到的LRDs光谱和形态的一类有前景的模型是准星:围绕通过超大质量星(SMSs)坍缩形成的吸积黑洞的巨大包层。然而,经典的SMS路径依赖于高度受限的环境和结构条件:强的Lyman-Werner(LW)背景以抑制H$_2$冷却,高且持续的气体流入率以强制熵分层包层,并假设非零旋转支撑以防止在$\sim 10^6 M_{\odot}$之前发生GR不稳定性坍缩。这里我们表明,由暗物质(DM)湮灭而非核燃烧提供能量的超大质量暗星(SMDSs)自然满足准星(QS)形成的关键结构和能量要求,同时放宽了上述所有限制条件。此外,通过SMDS路径形成的准星诞生时即具有前身质量$10\%$以上的即时黑洞质量。因此,它们直接进入晚期准星阶段;随后包层膨胀并冷却,直到其光球达到零金属度不透明度极限$(T_{ m eff}\sim3000$-$6000\,{ m K})$。这些冷的、光学厚的、未分辨的光球可以再现许多JWST LRDs的关键特征。

英文摘要

The nature of the ``Little Red Dots'' (LRDs) is one of the most profound mysteries posed by the JWST data. One promising class of models that can reproduce the observed LRDs spectra and morphology are quasi-stars: massive envelopes surrounding accreting black holes formed via the collapse of supermassive stars (SMSs). However, the canonical SMS pathway relies on a highly restricted set of environmental and structural conditions: strong Lyman--Werner (LW) backgrounds to suppress H$_2$ cooling, high and sustained gas inflow rates to enforce entropy stratified envelopes, and assume non-zero rotational support in order to prevent GR instability collapse before $\sim 10^6 M_{\odot}$. Here we show that supermassive dark stars (SMDSs), powered by dark matter (DM) annihilation rather than nuclear burning, naturally satisfy the key structural and energetic requirements for quasi-star (QS) formation while relaxing {\it all} of those restrictive conditions listed above. Moreover, quasi-stars formed through the SMDS pathway are born with prompt BH masses ($\gtrsim 10\%$) of the progenitor mass. They therefore enter directly into a late-stage quasi-star regime; subsequently the envelope expands and cools until its photosphere reaches the zero-metallicity opacity limit $(T_{\rm eff}\sim3000$-$6000\,{\rm K}$). Those cool, optically thick, unresolved photospheres can reproduce key features of many JWST LRDs.

2606.02538 2026-06-02 hep-ph hep-ex

Comment on "QCD-factorization amplitudes from flavour symmetries: beyond the $SU(3)$ symmetric case''

评论“QCD因子化振幅来自味对称性:超越$SU(3)$对称情况”

Bhubanjyoti Bhattacharya, David London

AI总结 针对arXiv:2604.19612中关于$B \to PP$衰变($P \in \{\pi, K, \eta, \eta'\}$)的拟合,指出其声称的EWP-树关系(ETRs)无效是错误的,因为ETRs在SU(3)对称性下是群论上严格的,并指出该文形式主义的若干弱点。

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Comments
8 pages. Comment on arXiv:2604.19612
AI中文摘要

最近,使用结合拓扑图与QCD因子化的形式,对$B \to PP$衰变($P \in \{\pi, K, \eta, \eta'\}$)进行了拟合(arXiv:2604.19612,“QCD因子化振幅来自味对称性:超越$SU(3)$对称情况”),并得到了良好的拟合结果。我们最近也在假设$B \to PP$振幅由味SU(3)对称性关联的前提下进行了这样的拟合,但发现拟合效果很差。因此,这两个结果相互矛盾。这一矛盾的根源在于我们应用了EWP-树关系(ETRs)。这些关系是在约30年前推导的,它们将不同的拓扑图或约化矩阵元联系起来,从而减少了拟合中未知参数的数量。在他们的论文中,声称ETRs是无效的,因此使用它们的研究是不可靠的。我们撰写这篇评论是为了解释这一断言为何不正确。关键在于,ETRs在群论上是数学上严格的。如果SU(3)未被破坏,并且忽略弱有效哈密顿量中的小Wilson系数$c_{7,8}$,则ETRs自动成立且精确。也就是说,这是一个群论结果——不涉及任何强子计算。在这篇评论中,我们还指出了他们形式主义的若干弱点。

英文摘要

Recently, a fit to $B \to PP$ decays ($P \in \{π, K, η, η'\}$) was performed (arXiv:2604.19612, "QCD-factorization amplitudes from flavour symmetries: beyond the $SU(3)$ symmetric case''}) using a formalism that combines topological diagrams with QCD factorization, and a good fit was found. We also recently performed such a fit, under the assumption that the $B \to PP$ amplitudes are related by flavour SU(3) symmetry, but we found a very poor fit. The two results therefore disagree with one another. The source of this disagreement is that we applied EWP-tree relations (ETRs). These were derived $\sim 30$ years ago, and relate different topological diagrams or reduced matrix elements, thus reducing the number of unknown parameters in the fit. In their paper, it is asserted that ETRs are invalid, so that analyses that use them are unreliable. We are writing this Comment to explain why this assertion is incorrect. The key point is that ETRs are mathematically rigorous, group theoretically. If SU(3) is unbroken, and the small Wilson coefficients $c_{7,8}$ in the weak effective Hamiltonian are neglected, ETRs follow automatically and are exact. That is, this is a group theory result -- no hadronic calculations are involved. In this Comment, we also point out several weaknesses of their formalism.

2606.02537 2026-06-02 physics.soc-ph cs.SI

A Guide to Higher-Order Homophily

高阶同质性指南

Moritz Laber, Brennan Klein

AI总结 本文综述了超图中高阶同质性和异质性的量化方法及模型,为研究者提供方法论选择和未来发展的基础。

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AI中文摘要

同质性(相似个体间交互的过度代表)和异质性(不同个体间交互的普遍增加)是社交网络中常见的混合模式。随着超图越来越多地用于表示社会系统,对同质性和异质性的高阶视角变得愈发重要。在此,我们提供对这一问题的两个互补视角:首先,我们调查了可用于量化超图中同质性(或异质性)的度量——强调与现有成对度量的概念差异——并通过深入示例解释每个度量。其次,我们概述了高阶混合模式的超图模型,区分了具有不同用例的几个模型家族。通过提供现有方法的指南并综合当前关于高阶同质性和异质性的知识体系,我们为知情的方法论选择和未来发展奠定了基础。

英文摘要

Homophily, the overrepresentation of interactions among similar individuals, and heterophily, the elevated prevalence of interactions among dissimilar ones, are frequently observed mixing patterns in social networks. As hypergraphs are increasingly used to represent social systems, a higher-order perspective on homophily and heterophily becomes ever more relevant. Here, we provide two complementary perspectives on this problem: First, we survey measures that can be used to quantify homophily (or heterophily) in hypergraphs -- emphasizing conceptual differences to existing pairwise measures -- and explain each measure through in-depth examples. Second, we provide an overview of hypergraph models for higher-order mixing patterns, distinguishing several model families with distinct use cases. By providing a guide to existing methods and synthesizing the current body of knowledge on higher-order homophily and heterophily, we lay the basis for informed methodological choices and future developments.

2606.02531 2026-06-02 quant-ph math.OA math.RT

Hybrid Clifford Codes via Operator Algebra Quantum Error Correction and Projective Representation Theory

混合 Clifford 码:基于算子代数量子纠错与投影表示理论

Jonas Eidesen, David W. Kribs, Andrew Nemec

AI总结 本文通过算子代数量子纠错框架和投影表示理论,将 Clifford 码推广到混合经典-量子信息与投影表示设置,提出了新的混合子空间和子系统 Clifford 码,并扩展了基本表示论量子纠错定理。

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Comments
23 pages
AI中文摘要

Clifford 码是基于表示论的量子稳定子码的自然推广。这类码先前已被扩展到量子子系统码的设置。我们针对混合经典和量子信息以及投影表示理论设置,提出了 Clifford 码的两重推广。这导致了新的混合子空间和子系统 Clifford 码类别。我们基于算子代数量子纠错框架,扩展了基本的表示论量子纠错定理以包含这些码。我们还讨论了整个过程中的几个例子,包括稳定子型和非稳定子型。

英文摘要

Clifford codes are a natural generalization of quantum stabilizer codes based primarily on representation theory. This class of codes has previously been extended to the setting of quantum subsystem codes. We formulate a two-fold generalization of Clifford codes, for both the hybrid classical and quantum information and projective representation theory settings. This leads to new classes of hybrid subspace and subsystem Clifford codes. We extend the fundamental representation theoretic quantum error correction theorem to include these codes, based on the operator algebra quantum error correction framework. We also discuss several examples throughout the presentation, of both stabilizer and non-stabilizer type.

2606.02524 2026-06-02 quant-ph physics.optics

Practical Limits on Integrated Squeezers

集成压缩器的实际限制

Devin J. Dean, Taewon Park, Lars S. Madsen, Alex Terrasson, Sam Robison, Geun Ho Ahn, Ziyu Wang, Hubert S. Stokowski, Luke Qi, Jesse J. Slim, Joel Corney, Darwin Serkland, Warwick P. Bowen, Martin M. Fejer, Amir H. Safavi-Naeini

AI总结 本文量化了集成光子学中压缩光测量所面临的各种噪声源的基本限制,并提出了一个通用模型来指导下一代集成压缩光系统的设计和基准测试。

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Journal ref
npj Nanophotonics (2026)
Comments
9 figures
AI中文摘要

最近的实验已经证明了利用集成光子学成功产生和检测中等压缩的真空态。然而,为了从高度压缩光的低噪声中受益,必须减轻许多不同的噪声源。在这里,我们量化了这些噪声源对压缩测量施加的基本限制,并发现不同平台和设计之间具有惊人的普遍性。我们将这些不同的限制组合成一个简单的模型,为下一代集成压缩光系统的设计和基准测试提供实用指导。

英文摘要

Recent experiments have demonstrated the successful generation and detection of moderately squeezed vacuum states with integrated photonics. However, in order to benefit from the reduced noise of highly squeezed light, many different noise sources must be mitigated. Here, we quantify the fundamental limits these noise sources impose on squeezing measurements and find surprising generality across different platforms and designs. We combine these different limitations into a simple model that provides practical guidance for the design and benchmarking of next-generation integrated squeezed-light systems.

2606.02520 2026-06-02 physics.geo-ph

How geometry of subduction zones correlates with earthquake dynamics

俯冲带几何形状如何与地震动力学相关

Oscar Y. L. Chau, Rebecca Bendick, Gary P. T. Choi, L. Mahadevan

AI总结 通过标度论证和曲面微分几何数据分析,研究俯冲带曲率与地震频率和震级的关系,发现平坦俯冲带易发生罕见大震,弯曲俯冲带易发生频繁小震。

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AI中文摘要

地球表面的俯冲带通常弯曲且局部化,其突然滑动导致地震。这些区域的几何形状如何影响巨型逆冲地震的发生?这里我们结合简单的标度论证和使用曲面微分几何的数据分析,来研究俯冲带的地震产出与其形状之间的关系。标度论证表明,相对于平面界面,界面曲率如何改变应力的积累和释放;沿相对平坦的俯冲带的一致滑动应导致罕见但大的事件,而弯曲的俯冲带应导致频繁的较小事件。为了验证这一点,我们利用全球几何数据集,分析俯冲带表面曲率与其中地震频率和震级之间的相关性。我们的分析表明,弱弯曲的板片几何形状与较罕见的较大震级事件相关,而曲率相对离散度较大的板片几何形状与频繁但较小震级的事件相关。使用俯冲带的不同尺度依赖形状指标,我们表明地震产出受到上覆板块和俯冲板块的一致性的影响。更广泛地说,我们的结果表明需要在计算模型和地震风险预测框架中纳入俯冲带的大尺度几何形状。

英文摘要

Subduction zones on the surface of the Earth, where abrupt sliding leads to earthquakes, are generally curved and localized. How does the geometry of these zones influence the occurrence of megathrust earthquakes? Here we use a combination of simple scaling arguments and data analysis using the differential geometry of surfaces to examine the relationship between the earthquake productivity of subduction zones and their shape. A scaling argument suggests how interface curvature changes both the accumulation and release of stress relative to planar interfaces; conformable sliding along relatively flat subduction zones should lead to rare but large events, while curved subduction zones should lead to frequent smaller events. To test this, we leverage global geometry datasets and analyze the correlation between the surface curvatures of the subduction zones and the frequency and magnitude of earthquakes therein. Our analysis shows that weakly curved slab geometries are associated with rarer larger magnitude events, while slab geometries with a larger relative dispersion in curvature are associated with frequent but smaller magnitude events. Using different scale-dependent shape metrics of the subduction zones, we show that the earthquake productivity is influenced by the conformability of the overriding and downgoing plates. More broadly, our results suggest the need to incorporate the large-scale geometry of subduction zones in computational models and predictive frameworks for earthquake risk.

2606.02516 2026-06-02 astro-ph.SR

On the Relationship between Solar Spicules and Propagating Coronal Disturbances: The Role of Shocks

关于太阳针状体与传播日冕扰动之间的关系:激波的作用

Ravi Chaurasiya, Sankalp Srivastava, Piyali Chatterjee, Sahel Dey, Robertus Erdélyi, Ankala Raja Bayanna

AI总结 通过观测和模拟,发现色球层激波驱动部分针状体,并在日冕中转化为大振幅压缩波,产生传播日冕扰动,从而将针状体形成与日冕扰动联系起来。

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Comments
16 pages, 13 figures. Accepted for publication in ApJ
AI中文摘要

针状体和传播日冕扰动是太阳大气中普遍存在的动态特征,然而它们之间的物理联系仍然是太阳大气质量和能量输运中一个至关重要但尚未解决的问题。利用瑞典1米太阳望远镜和太阳动力学观测站的同时多波长高分辨率观测,并辅以二维辐射磁流体动力学模拟,我们发现:i) 色球层中由非线性波陡化产生的激波驱动了一些针状体;ii) 在日冕中,这些激波可能根据磁场强度和周围日冕条件转变为大振幅非线性压缩磁流体动力学波。无论哪种情况,日冕中的激波或大振幅压缩波都会向上输运质量通量,并在日冕波段产生强度变化,表现为传播日冕扰动。此外,多高度小波分析显示,低色球层中主导的约5分钟周期在高大气层演变为更长周期(≥10分钟),这与分层介质中的色散传播一致。观测特征与数值模拟共同表明,激波驱动的磁流体动力学机制将针状体形成与日冕扰动联系起来。最后,来自观测和模拟的质量通量估计表明,这些传播日冕扰动也有助于向太阳风供应质量。

英文摘要

Spicules and propagating coronal disturbances (PCDs) are ubiquitous dynamic features of the solar atmosphere, yet their physical connection remains an open question of paramount importance to the mass and energy transport in the solar atmosphere. Using concurrent multiwavelength high-resolution observations from the Swedish 1-m Solar Telescope and the Solar Dynamics Observatory, supported with two-dimensional radiative magnetohydrodynamic (MHD) simulations, we find that i) shock waves in the chromosphere generated from non-linear wave steepening drive some spicules, ii) in the corona, these shock waves may transition into large amplitude non-linear compressive MHD waves depending on the magnetic field strength and the ambient coronal conditions. In either case, the shocks or the large-amplitude compressive waves in the corona, also transport upward mass flux and produce intensity variations in the form of PCDs in coronal passbands. Further a multi-height wavelet analysis shows dominant $\sim$5 minute periods in the lower chromosphere that evolve into longer periods ($\ge$10 minutes) at higher atmospheric layers, consistent with dispersive propagation in a stratified medium. The observational characteristics together with the numerical simulations, demonstrate that a shock-driven MHD mechanism links spicule formation to coronal disturbances. Finally, mass flux estimates from both the observations and the simulations indicate that these PCDs can also aid in supplying mass to the solar wind.

2606.02512 2026-06-02 cond-mat.dis-nn cond-mat.stat-mech nlin.AO physics.bio-ph

Frustrated neurons: Energy landscapes and relaxation dynamics in repulsive phase oscillators

受挫神经元:排斥性相位振荡器中的能量景观与弛豫动力学

Brandon B. Le

AI总结 本文借鉴凝聚态物理中的几何受挫概念,将排斥耦合的节律单元映射为反铁磁XY模型,分析三角形、四面体和kagome晶格等几何结构中的相位动力学,发现零温弛豫抑制全局同步但选择低能亚稳态扭矩平衡态,并指出神经系统中弱全局相干性可能反映受挫动力学景观下的结构化局部时序。

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Comments
39 pages, 15 figures
AI中文摘要

几何受挫是凝聚态物理中的一个核心范式,它为那些局部偏好相互作用无法全局兼容的系统提供了统一语言。本文利用这一语言,构建了受挫神经时序的最小理论,将排斥耦合的节律单元映射到反铁磁XY模型。在此框架下,凝聚态中的局域约束、简并基态流形、亚稳态和淬火动力学等概念成为结构化神经相位动力学的具体诊断工具。我们分析了一系列几何结构:三角形作为最小受挫基序,具有两种手性120°时序态;四面体,其约化基态流形由与对极点配对相关的相交连续分支组成;以及kagome晶格,其上局域约束定义了一个受限的三着色流形。kagome晶格揭示了核心动力学结果:零温弛豫抑制了全局同步,但通常选择低能亚稳态扭矩平衡态而非精确基态。最后,我们展示了如何将相位理论作为有效相互作用目标,回推到生物物理神经模型,其中几何时序受挫通过围绕闭合基序变得不兼容的优选相位延迟来实现。这一视角表明,神经系统中弱的全局相干性不一定标志着无序活动,而可能反映了由受挫动力学景观塑造的结构化局部时序秩序。

英文摘要

Geometrical frustration, a central paradigm in condensed matter physics, provides a unifying language for systems in which locally preferred interactions cannot be made globally compatible. Here, we use this language to formulate a minimal theory of frustrated neural timing, mapping repulsively coupled rhythmic units onto antiferromagnetic XY models. Within this framework, the condensed-matter concepts of local constraints, degenerate ground-state manifolds, metastability, and quench dynamics become a concrete diagnostic framework for structured neural phase dynamics. We analyze a hierarchy of geometries: a triangle as the minimal frustrated motif with two chiral 120° timing states, a tetrahedron whose reduced ground-state manifold consists of intersecting continuous branches associated with antipodal pairings, and a kagome lattice on which local constraints define a constrained three-coloring manifold. The kagome lattice reveals the central dynamical result: zero-temperature relaxation suppresses global synchrony but typically selects low-energy metastable torque-balanced states rather than exact ground states. Finally, we show how the phase theory can be carried back towards biophysical neural models by treating it as an effective-interaction target, where geometrical timing frustration is realized through preferred phase lags that become incompatible around closed motifs. This perspective suggests that weak global coherence in neural systems does not necessarily signal disordered activity, but can reflect structured local timing order shaped by a frustrated dynamical landscape.

2606.02511 2026-06-02 gr-qc astro-ph.HE astro-ph.SR hep-ph

Dyonic Quark Stars in Quasi-Topological Electromagnetism

准拓扑电磁学中的双荷夸克星

Michael Gammon, Nicola De Kock, Robert B. Mann, Amos Kubeka

AI总结 本文在准拓扑电磁学框架下研究双荷夸克星解,发现双荷电荷分布不仅使特征“钩”形向更大质量和半径移动,还诱导出具有负压外壳和正压核心的第二分支,最终形成“回形针”形状。

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AI中文摘要

在本文中,我们考虑了Liu等人[Liu_2019]最近提出的暗能量形式——准拓扑电磁学(QTEM)中的夸克星解。由于QTEM贡献对于纯电/磁荷是平凡的,我们考虑纯QTEM中的双荷情况,这确实从非线性理论中诱导出(暗)非平凡动力学。除了引入双荷电荷分布通常将特征夸克星“钩”形推向更大的质量和半径外,它还导致具有小双荷电荷比的恒星在非常大的质量和半径处出现第二个分支。这第二组解具有包围正压核心的负压外壳。当我们探索参数空间时,这些特征以有趣的方式相互作用和演化,两个分支最终在$M/R$空间中合并,然后随着双荷电荷比变大而稳定成特征性的“回形针”形状。

英文摘要

In this paper we consider quark star solutions to Liu et al.'s \cite{Liu_2019} quasi-topological electromagnetism (QTEM), a recently proposed form of dark energy. Since the QTEM contribution is trivial for pure electric/magnetic charge, we consider the dyonic case in pure QTEM which does induce (dark) non-trivial dynamics from the non-linear theory. Besides the introduction of a dyonic charge distribution generally pushing the characteristic quark star `hook' shape to larger masses and radii, it also induces a second branch at very large mass and radius for stars with a small dyonic charge ratio. This second set of solutions have a negative pressure envelope surrounding a positive pressure core. As we explore the parameter space these features interact and evolve in interesting ways, with the two branches eventually merging in $M/R$ space before settling into a characteristic `paperclip' shape as the dyonic charge ratio becomes large.

2606.02507 2026-06-02 cond-mat.mtrl-sci cs.ET cs.LG physics.app-ph physics.comp-ph

Towards Automated Discovery: A Review of Generative Models, Multimodal Learning and Closed-Loop Workflows in Inverse Materials Design

迈向自动发现:逆向材料设计中生成模型、多模态学习与闭环工作流综述

Anand Babu, Rogério Almeida Gouvêa, Gian-Marco Rignanese

AI总结 本文综述了逆向材料设计中生成晶体结构建模、多模态学习和闭环设计管道的最新进展,重点讨论了可行性约束与物理先验的施加方式、多模态融合策略以及多种逆向设计策略(如条件生成与潜在优化、贝叶斯优化、强化学习和主动学习),并指出了常见失败模式及基于分阶段报告的评估实践。

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AI中文摘要

逆向材料设计将材料发现从正向预测转变为在物理约束下满足目标的有针对性的候选材料提出。在此,我们回顾了晶体固体中生成晶体结构建模、多模态学习和闭环设计管道的最新进展。我们调查了现代生成器如何从大型数据库中学习化学-结构先验,以实现周期性结构的可控采样,并比较了包括变分自编码器、归一化流、自回归公式和扩散模型在内的主要模型类别。特别关注如何通过表示选择、训练目标、采样时指导以及生成后筛选和弛豫,在整个工作流中施加可行性约束和物理先验。我们还讨论了多模态学习如何融合多种材料模态,包括晶体结构、热力学、电子信息、显微镜、光谱学、加工背景和科学文本,以构建更通用、可迁移的化学空间表示。此外,考察了多种逆向设计策略,特别是那些将条件生成与潜在优化、贝叶斯优化、强化学习和主动学习相结合的策略。最后,我们强调了反复出现的失败模式,如代理利用、多样性崩溃、分布偏移和稳定性-可合成性差距,并基于有效性、新颖性、独特性、稳定性和成本的分阶段报告,概述了发现级评估实践。

英文摘要

Inverse materials design is shifting materials discovery from forward prediction to targeted proposal of candidates that satisfy objectives under physical constraints. Here, we review recent advances in generative crystal structure modeling, multimodal learning, and closed-loop design pipelines for crystalline solids. We survey how modern generators learn chemical-structural priors from large databases to enable controllable sampling of periodic structures, and compare leading model classes including variational autoencoders, normalizing flows, autoregressive formulations, and diffusion models. Particular attention is given to how feasibility constraints and physical priors are enforced across the workflow, through representation choices, training objectives, sampling-time guidance, and post-generation screening and relaxation. We also discuss how multimodal learning fuses diverse materials modalities, including crystal structures, thermodynamic, electronic information, microscopy, spectroscopy, processing context, and scientific text, to construct a more universal, transferable representation of chemical space. In addition, diverse inverse-design strategies are examined, particularly those that integrate conditional generation with latent optimization, Bayesian optimization, reinforcement learning, and active learning. Finally, we highlight recurring failure modes, such as surrogate exploitation, diversity collapse, distribution shift, and the stability-synthesizability gap, and outline discovery-grade evaluation practices based on staged reporting of validity, novelty, uniqueness, stability, and cost.

2606.02505 2026-06-02 quant-ph cond-mat.stat-mech

Spatial and particle-particle entanglement in 1D quantum walks of two distinguishable or indistinguishable bosonic particles

两个可区分或不可区分玻色子粒子的一维量子行走中的空间和粒子-粒子纠缠

Christopher Mastandrea, Chih-Chun Chien

AI总结 通过Hubbard哈密顿量下的连续时间量子行走,研究两个可区分或不可区分玻色子粒子在空间分离区域和粒子之间的纠缠度量,分析不同初始态下纠缠的增长及长时极限随在位排斥的非单调变化。

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Comments
15 pages, 8 figures, 2 tables
AI中文摘要

我们提出了由Hubbard哈密顿量支配的一维双粒子连续时间量子行走中,空间分离区域之间以及两个可区分或不可区分粒子之间的纠缠度量。左右纠缠检查粗粒化态的熵,该态计数晶格左半部分和右半部分的粒子数,而粒子-粒子纠缠基于时间演化Fock态的奇异值熵。使用可分离、纠缠和双占据初始态,我们检查了初始纠缠以及不同纠缠度量中的后续增长。虽然当初始态可比较时,不可区分情况的纠缠度量类似于可区分情况,但纠缠度量的长时极限通常随着在位排斥的增加而呈现非单调性。我们还讨论了对未来多粒子量子动力学中纠缠研究的可能启示。

英文摘要

We present entanglement measures between spatially separated regions and between two distinguishable or indistinguishable particles in one-dimensional two-particle continuous-time quantum walks governed by the Hubbard Hamiltonian. The left-right entanglement checks the entropy of coarse-grained states counting the numbers of particles on the left and right halves of the lattice while the particle-particle entanglement is based on the entropy of the singular values of the time-evolved Fock state. With separable, entangled, and doubly occupied initial states, we examine initial entanglement and the following growth in different entanglement measures. While the entanglement measures of the indistinguishable cases resemble those of the distinguishable cases when the initial states are comparable, the long-time limits of the entanglement measures are typically non-monotonic as the onsite repulsion increases. We also discuss possible implications for future research of entanglement in multi-particle quantum dynamics.

2606.02504 2026-06-02 quant-ph

Closed-loop Structure of Quantum Probabilities from Unitarity

从幺正性导出的量子概率的闭环结构

M. J. Rave

AI总结 本文证明量子概率的闭环分解是幺正性的直接结果,Bargmann不变量自然作为与这些环相关的相位不变量出现,并将干涉解释为不同类别闭环的贡献,同时指出Born规则反映了正向和反向振幅乘积的基本二次结构。

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AI中文摘要

在先前的工作(Rave, 2008)中,提出闭环应被视为基本的量子实体,并在准概率框架中呈现了这样的环。我们证明量子概率的闭环分解是幺正性的直接结果,并且Bargmann不变量自然地作为与这些环相关的相位不变量出现,而不是独立引入的。这将干涉识别为不是神秘的交叉项,而是由不同类别的闭环的贡献,这些环由其相关的Bargmann相位加权。此外,Born规则被视为反映了由正向和反向振幅乘积产生的基本二次结构,这些振幅共同定义了这样的环。

英文摘要

In previous work (Rave, 2008) it was proposed that closed loops should be treated as fundamental quantum entities, and such loops were presented in a quasi-probability framework. We demonstrate that the closed-loop decomposition of quantum probabilities is a direct consequence of unitarity, and that Bargmann invariants arise naturally as the phase-invariant quantities associated with these loops, rather than being introduced independently. This identifies interference not as mysterious cross terms, but as contributions from distinct classes of closed loops weighted by their associated Bargmann phases. Additionally, the Born rule is seen to reflect the fundamental quadratic structure arising from the product of forward and reverse amplitudes, which together define such loops.

2606.02501 2026-06-02 cond-mat.str-el cond-mat.mes-hall

Electrical observation via spin Seebeck effect of fractionalized excitations in a magnetic insulator

通过磁性绝缘体中分数化激发子的自旋塞贝克效应进行电学观测

Nan Tang, Josef Willsher, Stephan Glamsch, Aisha Aqeel, Ludwig Scheuchenpflug, Michael Schulze, Christoph Liebald, Daniel Rytz, Christo Guguschev, Manfred Albrecht, Roderich Moessner, Philipp Gegenwart

AI总结 利用自旋塞贝克效应探测非共线伊辛磁体Dy2Ti2O7中的涌现磁单极子,观察到单极子增殖时的特征峰,扩展了自旋电子学方法在检测奇异激发中的应用。

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Comments
This version supersedes the previous version, arXiv:2509.18422, with one additional figure in the main text, corrected errors, an expanded author list, the inclusion of a theoretical model, and other minor revisions. 39 pages, 4+5 figures
AI中文摘要

分数化激发子是量子物质中涌现现象最显著的标志之一。尽管在受挫磁体中广泛寻找,但它们的检测和表征仍然具有挑战性,这促使人们探索新的探测手段。同时,自旋电子学为探测自旋相关现象提供了多功能工具。特别是,自旋塞贝克效应(SSE)将热驱动的磁激发转换为相邻金属中的电压,从而提供对底层动力学和输运性质的电学访问。在这里,我们利用SSE探测非共线伊辛磁体Dy$_2$Ti$_2$O$_7$中的涌现磁单极子,这是三维分数化磁体的罕见实例。我们观察到SSE信号在单极子增殖处出现显著峰值,并伴有特征频率和角度依赖性。我们的结果拓宽了自旋电子学方法检测奇异激发的范围,为磁性绝缘体一般和单极子物理提供了新见解,并暗示了量子材料作为功能界面的潜力。

英文摘要

Fractionalized excitations are among the most striking signatures of emergence in quantum matter. While widely sought in frustrated magnets, their detection and characterization remain challenging, motivating the exploration of new probes. Meanwhile, Spintronics offers versatile tools for probing spin-related phenomena. In particular, the spin Seebeck effect (SSE) converts thermally driven magnetic excitations into a voltage in an adjacent metal, providing electrical access to the underlying dynamics and transport properties. Here we employ the SSE to probe emergent magnetic monopoles in the non-collinear Ising magnet Dy$_2$Ti$_2$O$_7$, a rare instance of a three-dimensional fractionalized magnet. We observe an SSE signal featuring a pronounced peak at monopole proliferation, accompanied by characteristic frequency and angular dependence. Our results broaden the scope of spintronic methods for detecting exotic excitations, provide new insights into magnetic insulators generally and monopole physics specifically, and suggest the potential of quantum materials as functional interfaces.

2606.02500 2026-06-02 physics.atom-ph cond-mat.quant-gas quant-ph

Creating and Probing Spin-Squeezed States of Molecules

创建和探测分子的自旋压缩态

Connor M. Holland, Callum L. Welsh, Yukai Lu, David Wellnitz, Xing-Yan Chen, Ana Maria Rey, Lawrence W. Cheuk

AI总结 利用光镊阵列中的极性CaF分子,通过偶极交换相互作用实现自旋压缩态,并展示其计量增益和量子关联。

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Comments
main text: 8 pages, 4 figures; supplementary material: 18 pages, 8 figures, 4 tables
AI中文摘要

极性分子因其强长程偶极相互作用、对电磁场的广泛敏感性以及对标准模型之外物理的敏感性,成为量子增强传感和基础物理精密测试的有前景平台。然而,在分子系统中产生计量上有用的纠缠态一直难以实现。在这里,我们报告了在光镊阵列中捕获的极性CaF分子中首次观察到一类计量上有用的纠缠态——自旋压缩态。自旋自由度编码在通过偶极交换相互作用直接耦合的转动能级中。通过利用合适的动态解耦方案,我们从直接交换相互作用中观察到高达3.0(3)dB的计量增益(未经测量校正为2.2(3)dB)。利用Floquet工程,我们进一步实现了更丰富的哈密顿量,在保持自旋压缩的同时,促进了更长程量子关联的发展。通过位置和自旋分辨测量,我们证明这些纠缠态增强了对均匀场和空间变化场的敏感性,并揭示了强的非经典关联,包括二分纠缠和爱因斯坦-波多尔斯基-罗森操控。最后,我们将自旋压缩态转移到长寿命且无相互作用的超精细态中,其中计量增强持续长达100毫秒。我们的结果建立了分子光镊阵列作为生成、控制、表征和存储分子纠缠态的可扩展平台,为量子增强传感和基础物理精密测试开辟了新机遇。

英文摘要

Polar molecules are a promising platform for quantum-enhanced sensing and precision tests of fundamental physics, owing to their strong long-range dipolar interactions, broad sensitivity to electromagnetic fields, and sensitivity to potential physics beyond the Standard Model. However, the creation of metrologically useful entangled states in molecular systems has remained elusive. Here, we report the first observation of a class of metrologically useful entangled states - spin-squeezed states - in polar CaF molecules trapped in an optical tweezer array. The spin degree of freedom is encoded in rotational levels which are directly coupled by dipolar exchange interactions. By harnessing appropriate dynamical decoupling schemes we observe up to 3.0(3)dB of metrological gain, (2.2(3)dB without measurement correction) from direct exchange interactions. Using Floquet engineering, we further realize richer Hamiltonians that preserve spin squeezing while enabling the development of longer-range quantum correlations. Using site- and spin-resolved measurements we demonstrate that these entangled states enhance sensitivity to both homogeneous and spatially varying fields, and reveal strong non-classical correlations, including bipartite entanglement and Einstein-Podolsky-Rosen steering. Finally, we transfer the spin-squeezed states into long-lived and non-interacting hyperfine states, where the metrological enhancement persists for up to 100ms. Our results establish molecular optical tweezer arrays as a scalable platform for generating, controlling, characterizing, and storing entangled states of molecules, opening new opportunities for quantum-enhanced sensing and precision tests of fundamental physics.

2606.02499 2026-06-02 astro-ph.SR

Evaluating Cepheid Metallicity Effect Determinations via IC1613 and Gaia-independent Parallaxes

通过IC1613和独立于Gaia的视差评估造父变星金属丰度效应测定

Daniel Majaess

AI总结 利用18个HST视差统一建立独立于Gaia的IC1613距离,并基准测试三种造父变星金属丰度校正,发现较大校正不被支持,需更广泛金属丰度基线和更多非Gaia视差来检验较小校正。

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Comments
To appear in publication
AI中文摘要

18个银河系经典造父变星的HST视差被统一,以建立独立于Gaia的IC1613距离并评估金属丰度效应测定,因为Gaia零点存在争议。最近提出的经典造父变星金属丰度校正$γ(W_{VI}) \simeq 0, -0.25, -0.50$ mag dex$^{-1}$被基准测试,并得到$μ_{0,{W_{VI}}} \simeq 24.39, 24.16, 23.93$ ($\pm0.07$)。相对于IC1613 TRGB和TRGB/JAGB距离的加权平均值$24.39^{+0.07}_{-0.04}$ (EDD) 和 $24.36\pm0.06$/$24.45\pm0.11$ (CCHP),较大的校正不被支持。需要更广泛的金属丰度基线来检验较小的校正(例如,$γ(W_{VI}) \lesssim -0.1$ mag dex$^{-1}$),同时获取额外的非Gaia视差,因为存在关于DR3的已发表问题(例如,关键的长周期造父变星S Vul, SV Vul)。

英文摘要

18 HST parallaxes for Galactic classical Cepheids are unified to establish a Gaia-independent IC1613 distance and evaluate metallicity effect determinations, since the Gaia zeropoint is debated. Recently proposed classical Cepheid metallicity corrections of $γ(W_{VI}) \simeq 0, -0.25, -0.50$ mag dex$^{-1}$ are benchmarked, and yield $μ_{0,{W_{VI}}} \simeq 24.39, 24.16, 23.93$ ($\pm0.07$). Larger corrections are disfavored relative to a weighted mean of IC1613 TRGB and TRGB/JAGB distances of $24.39^{+0.07}_{-0.04}$ (EDD) and $24.36\pm0.06$/$24.45\pm0.11$ (CCHP). A more expansive metallicity baseline is desirable to scrutinize smaller corrections (e.g., $γ(W_{VI}) \lesssim -0.1$ mag dex$^{-1}$), while concurrently acquiring additional non-Gaia parallaxes since published concerns exist regarding DR3 (e.g., critical long-period Cepheids S Vul, SV Vul).

2606.02496 2026-06-02 math.MG math-ph math.DG math.MP

Timelike ideal boundary of non-positively curved Lorentzian spaces

非正曲率洛伦兹空间的类时理想边界

Saúl Burgos, Mauricio Che, Miguel Prados-Abad

AI总结 本文引入洛伦兹长度空间的类时理想边界概念,定义为未来或过去方向类时测地射线的渐近类集合,并赋予其锥拓扑和角度度量,建立了度量空间的上曲率界,最后以广义锥为模型研究了类时理想边界与纤维的度量理想边界及翘曲函数渐近行为的关系。

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Comments
54 pages, 9 figures
AI中文摘要

我们引入洛伦兹长度空间的类时理想边界概念,作为未来或过去方向类时测地射线的渐近类集合,这一构造补充了Geroch-Kronheimer-Penrose意义上的因果边界,类似于度量空间的理想边界概念。我们赋予这样的类时理想边界一个自然的锥拓扑和一个角度度量,并建立了所得度量空间的上曲率界。最后,我们考虑广义锥作为模型,研究了类时理想边界与纤维的度量理想边界以及翘曲函数的渐近行为之间的关系。

英文摘要

We introduce the notion of timelike ideal boundary of a Lorentzian length space as the set of asymptotic classes of future or past-directed timelike geodesic rays, a construction complementary to the causal boundary in the sense of Geroch-Kronheimer-Penrose and akin to the concept of ideal boundary of a metric space. We endow such a timelike ideal boundary with a natural cone topology and an angular metric, and establish upper curvature bounds for the resulting metric space. Finally, we consider generalized cones as a model and study the relation between the timelike ideal boundary and both the metric ideal boundary of the fiber and the asymptotic behaviour of the warping function.

2606.02489 2026-06-02 cond-mat.quant-gas cond-mat.mes-hall quant-ph

Thouless Pumping of Large Chern Numbers in Optical Floquet Quasicrystals

光学Floquet准晶中大陈数的Thouless泵浦

Shien Wan, Zecheng Li, Bo Song

AI总结 本文提出在冷原子光学Floquet准晶中实现大陈数的方案,并通过Thouless泵浦直接测量,利用能隙标定定理表征陈数,揭示了输运特性与准能谱的联系。

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Comments
15 pages, 11 figures
AI中文摘要

陈数是关联和拓扑现象的核心,但大多数拓扑系统对应的陈数量级为1。本文提出了一种在冷原子光学Floquet准晶中实现大陈数的方案,可通过Thouless泵浦直接测量。我们研究了Floquet准晶的准能谱,并利用能隙标定定理表征了涌现的陈数。我们进一步研究了不同驱动频率和振幅下Floquet准晶中的Thouless泵浦,揭示了输运特性与准能谱之间的联系。我们的发现为探索Floquet准晶中丰富的拓扑动力学以及实现分数量子陈绝缘态开辟了新途径。

英文摘要

Chern numbers are central to correlated and topological phenomena, yet most topological systems are associated with Chern numbers of order unity. Here we propose a scheme to achieve large Chern numbers in an optical Floquet quasicrystal with cold atoms, which can be directly measured via Thouless pumping. We study the quasienergy spectrum of Floquet quasicrystals and characterize the emergent Chern numbers using gap labeling theorem. We further investigate the Thouless pumping in the Floquet quasicrystal at different driving frequencies and amplitudes, revealing the connection between transport features and the quasienergy spectrum. Our findings open new avenues for exploring rich topological dynamics in Floquet quasicrystals and realizing fractional Chern insulating states.

2606.02485 2026-06-02 hep-ph hep-th

On the spanning cuts consistency problem in the IBP reductions of Feynman integrals

费曼积分IBP约化中的跨切割一致性问题的研究

Zihao Wu, Yingxuan Xu

AI总结 本文揭示了费曼积分IBP约化中跨切割系数不一致的机制,指出切割引入的pinch奇异性抵消了消失的费曼规范参数,导致隐藏项变为有限,忽略这些项是误差来源,并提出了寻找线性隐藏关系的算法。

详情
Comments
24 pages, 5 figures, 32 tables
AI中文摘要

跨切割方法是一种在计算费曼积分时降低IBP约化成本的有效方法。然而,由于所谓的一致性问题,其使用受到限制。目前尚不清楚为什么不同切割之间的IBP约化系数可能不一致。在本文中,我们报告了这种不一致背后的机制。我们发现,如果盲目地忽略关系中与“消失”的费曼规范参数成比例的隐藏项,则切割下的IBP关系可能被违反。在某些情况下,切割引入了pinch奇异性,这些奇异性抵消了消失的费曼规范参数,使得隐藏项变为有限。在各种情况下,误差来自忽略这些有限的隐藏项。我们还声称,切割下的pinch奇异性与传播子之间的某些隐藏关系有关。在本文中,我们提供了一种算法及其实现来寻找线性隐藏关系。

英文摘要

The spanning cuts method is a powerful approach to reduce the cost of IBP reduction while computing Feynman integrals. However, its usage is limited due to the so-called consistency problem. It was unclear why the IBP reduction coefficients can be inconsistent with each other between different cuts. In this paper, we report a mechanism behind this inconsistency. We found that the IBP relations can be violated under the cuts, if we blindly erase the hidden terms that are proportional to the ``vanishing'' Feynman prescription parameters in the relations. In some cases, the cut introduces pinch singularities, which cancel the vanishing Feynman prescription parameters, making the hidden terms finite. In various cases, the error comes from omitting such finite hidden terms. We also claimed that the pinch singularity under the cuts are related to some hidden relations between the propagators. In this paper, we provide an algorithm and its implementation to find the linear hidden relations.

2606.02476 2026-06-02 cond-mat.mes-hall cond-mat.dis-nn

Leveraging structural disorder to enhance topological phases

利用结构无序增强拓扑相

Laura Gomez Paz, Peru d'Ornellas, Adolfo G Grushin

AI总结 通过数值模拟发现,在二维中惩罚原子近邻的结构无序可增强拓扑相,但在三维中结构无序普遍有害,并利用基于时间反演对称算符的谱局域化方法克服了自旋参考系无序对拓扑标记的干扰。

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Comments
19 pages, 13 figures
AI中文摘要

在位无序可以诱导从平庸绝缘体到拓扑绝缘体的转变。然而,在没有在位无序的情况下,结构无序是否有助于类似的转变,以及哪种结构无序更有利,尚不清楚。我们数值表明,在二维中,如果惩罚原子位点彼此靠近,结构无序可以增强并维持拓扑相直到强无序。然而,我们发现这种效应在三维中不存在,其中结构无序通常对该相有害。在我们的计算中,我们包含了可以扰乱全局自旋参考系的无序,这是一种在强无序固体中预期存在的被忽视的无序类型。这种无序致命地扰乱了自旋-Bott和自旋-Chern标记正确诊断拓扑相所需的信息。通过使用谱局域化,一种直接使用时间反演对称算符而非自旋投影定义的局部标记,我们展示了如何规避这一限制,为计算Z2不变量提供了基无关的理论。我们的工作表明,并非所有结构无序对拓扑同样有利,并突出了在固态和超材料实现中增强和检测拓扑相的指导原则。

英文摘要

On-site disorder can be leveraged to induce a transition from a trivial to a topological insulator. However it is unclear if structural disorder in the absence of on-site disorder can aid a similar transition and, if so, which kind of structural disorder is more favourable. We numerically show that structural disorder can enhance and sustain a topological phase up to strong disorder in two dimensions provided that one penalises atomic sites from being close to one another. However, we find this effect is absent in three dimensions, where structural disorder appears generically detrimental to the phase. In our calculations we include disorder that can scramble the global spin-reference frame, an overlooked type of disorder expected to exist in strongly disordered solids. This disorder fatally scrambles the information necessary for the spin-Bott and the spin-Chern marker to correctly diagnose a topological phase. By using the spectral localizer, a local marker directly defined using the time-reversal symmetry operator rather than a spin-projection, we show how one can circumvent this limitation, providing a basis-indifferent theory for calculating Z2 invariants. Our work showcases that not all structural disorders are equally beneficial to topology, and highlights guiding principles to enhance and detect topological phases in both solid-state and metamaterial realisations.

2606.02474 2026-06-02 physics.chem-ph

Approximating Hartree-Fock theory via an efficiently local reformulation

通过高效局部重整化近似Hartree-Fock理论

Trine Kay Quady, Eric Neuscamman

AI总结 本文提出一种重整化框架,通过成对局部自由度与自然局部解条件,实现分子轨道局部性约束下的高效自洽场优化,并测试了反应匹配方案,在中等分子中取得竞争性计算时间,且对HF和MP2反应能预测影响极小。

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Comments
12 pages of text, 21 pages of SI, 6 figures
AI中文摘要

我们探索了一种重整化的Hartree-Fock方程框架,该框架允许在分子轨道上施加不同程度的局部性模式,同时保持高效的自洽场优化算法。我们的重整化不是限制轨道的扩展并在这些限制内变分最小化能量,而是巧妙地将每个局部自由度与一个本身具有自然局部解释的特定解条件配对。这些配对可以各自开启或关闭,并且无论用于做出这些选择的稀疏模式如何,整体方法都保持快速的自洽场优化。我们利用这种结构测试了用于施加轨道局部性的反应匹配方案,并通过利用这种局部性的Fock构建,即使在中等大小的分子中也实现了有竞争力的计算时间。我们的初步测试还表明,这种施加轨道局部性的方法可以安排得对Hartree-Fock和MP2反应能预测的损害最小。

英文摘要

We explore a reorganized framework for the Hartree Fock equations that allows varying patterns of locality to be imposed on the molecular orbitals while maintaining a highly efficient self-consistent field optimization algorithm. Rather than limiting orbitals' spread and then variationally minimizing the energy within those limits, our reorganization neatly pairs each local degree of freedom with a specific solution condition that itself has a naturally local interpretation. These pairs can each be turned on or off, and, regardless of the sparsity pattern used to make such choices, the overall method maintains a fast self-consistent field optimization. We use this structure to test reaction-matched schemes for imposing orbital locality and, through Fock builds that exploit this locality, achieve competitive timings even in modestly sized molecules. Our initial tests also suggest that this approach to imposed orbital locality can be arranged so as to do minimal damage to both Hartree Fock and MP2 reaction energy predictions.